Particles in a gas are far apart compared to a solid or liquid, allowing it not to have a definitive shape or volume. This also means that gases can fill any container and be easily compressed.
Answer:
Repeated SN2 reactions occur leading to the formation of a racemic mixture
Explanation:
S-2-iodooctane is a chiral alkyl halide with an asymmetric carbon atom. The presence of an asymmetric carbon atom implies that it can rotate plane polarized light and thus lead to optical isomerism. The two configurations of the compound are R/S according to the Cahn-Prelong-Ingold system.
However, when S-2-iodooctane is treated with sodium iodide in acetone, repeated SN2 reactions occur since the iodide ion is both a good nucleophile and a good leaving group. Hence a racemic modification is formed in the system with time hence we end up with (±)- Iodooctane.
Answer:
for the given reaction is -99.4 J/K
Explanation:
Balanced reaction: 
![\Delta S^{0}=[1mol\times S^{0}(NH_{3})_{g}]-[\frac{1}{2}mol\times S^{0}(N_{2})_{g}]-[\frac{3}{2}mol\times S^{0}(H_{2})_{g}]](https://tex.z-dn.net/?f=%5CDelta%20S%5E%7B0%7D%3D%5B1mol%5Ctimes%20S%5E%7B0%7D%28NH_%7B3%7D%29_%7Bg%7D%5D-%5B%5Cfrac%7B1%7D%7B2%7Dmol%5Ctimes%20S%5E%7B0%7D%28N_%7B2%7D%29_%7Bg%7D%5D-%5B%5Cfrac%7B3%7D%7B2%7Dmol%5Ctimes%20S%5E%7B0%7D%28H_%7B2%7D%29_%7Bg%7D%5D)
where
represents standard entropy.
Plug in all the standard entropy values from available literature in the above equation:
![\Delta S^{0}=[1mol\times 192.45\frac{J}{mol.K}]-[\frac{1}{2}mol\times 191.61\frac{J}{mol.K}]-[\frac{3}{2}mol\times 130.684\frac{J}{mol.K}]=-99.4J/K](https://tex.z-dn.net/?f=%5CDelta%20S%5E%7B0%7D%3D%5B1mol%5Ctimes%20192.45%5Cfrac%7BJ%7D%7Bmol.K%7D%5D-%5B%5Cfrac%7B1%7D%7B2%7Dmol%5Ctimes%20191.61%5Cfrac%7BJ%7D%7Bmol.K%7D%5D-%5B%5Cfrac%7B3%7D%7B2%7Dmol%5Ctimes%20130.684%5Cfrac%7BJ%7D%7Bmol.K%7D%5D%3D-99.4J%2FK)
So,
for the given reaction is -99.4 J/K
C = pK
<span>C = 4.4E-4*0.032 = about 1.41E-5 </span>
<span>H2CO3 ==> H^+ + HCO3^- </span>
<span>k1 = (H^+)(HCO3^-)/(H2CO3) </span>
<span>(H^+)= (HCO3^-) = x </span>
<span>(H2CO3) = 1.41E-5 </span>
<span>Solve for x = (H^+) and convert to pH. </span>