First, recognize that this is an elimination reaction in which hydroxide must leave and a double bond must form in its place. It is likely an E2 reaction. Here is an efficient mechanism:
1) Pre-reaction: Protonate the -OH to make it a good leaving group, water. H2SO4 or any strong H+ donor works. The water is positively charged but still connected to the compound.
2) E2: Use a sterically hindered base, such as tert-butoxide (tButO-) to abstract the hydrogen from the secondary carbon. [You want a sterically hindered base because a strong, non-sterically hindered base could also abstract a hydrogen from one of the two methyl groups on the tertiary carbon, and that leads to unwanted products, which is not efficient]. As the proton of hydrogen is abstracted, water leaves at the same time, creating an intermediate tertiary carbocation, and the 2 electrons in the C-H bond immediately are used to make a double bond towards the partial positive charge.
In the products we see the major product and water, as expected. Even though you have an intermediate, remember that an E2 mechanism technically happens in one step after -OH protonation.
The general equation for radioactive decay is;
N = N₀e^(-λt)
x - decay constant (λ) - rate of decay
t- time
N - amount remaining after t days , since we are calculating the half life, amount of time it takes for the substance to to be half its original value, its N₀/2
N₀ - amount initially present
substituting the values
N₀/2 = N₀e^(-0.081t)
0.5 = e^(-0.081t)
ln (0.5) = -0.081t
-0.693 = -0.081t
t = 0.693 / 0.081
= 8.55
half life of substance is 8.55 days
Answer:
not sure if this is the right way to answer this question but PbS is Phosphate-buffered saline (i think)
Explanation:
A volatile acid is an acid that can leave solution and enter the atmosphere.
Answer:24.31
Explanation:Contribution made by isotope of mass 23.99= 23.99×78.99=1894.97
Contribution made by isotope of mass 24.99=24.99×10.00=249.9
Contribution made by isotope of mass 25.98=25.98×11.01=286.04
Total contribution=1894.97+249.9+286.04=2430.91
Average mass=2430.91÷100
=24.31
