What pressure, in atmospheres, is exerted on the body of a diver if he is 38 ft below the surface of the water when atmospheric
1 answer:
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The temperature of the system is 141.36K.
<h3><u>Explanation</u>:</h3>According to the universal gas law, the pressure of a gas is directly proportional to the absolute temperature and number of moles of the gas and inversely proportional to the volume of the gas.
So in equation format,
=constant.
Or= R.
Here R is called the universal gas constant which has different values in different units.
Here the unit of volume is in litres and unit of pressure is in atmosphere.
So. Value of R comes as =0.082057.
So, according to the question,
P is 5.8atm, V is 12 litres and n is 6 moles.
So, =
.
Or, T = .
Or, T = 141.36.
So,the temperature of the system is 141.36K
Answer: 1-Phenyl ethyl radical is formed as an intermediate in the reaction and since Phenyl ethyl radical has a trigonal planar geometry so it is a planar molecule having two faces. So Br radical radical can recombine with the two faces with equal probability leading to a racemic mixture in 50:50ratio of products.Hence two products are formed which are known as enatiomers.
Explanation:
When we irradiate the ethylbenzene with UV light , it leads to homolytic cleavage and 1- Phenyl ethyl free radical is generated.
Phenyl ethyl free radical is generated because it is very stable as it is on a secondary carbon center as well as on a benzylic position so it can be stabilized by the resonance as well as inductive effect at the secondary carbon center.
NBS(N-bromosuccinimide) is a source of bromine radical and provides bromine free radical.
Once the 1- Phenyl ethyl free radical is generated then bromine free radical can recombine with benzyl free radical leading to product formation.
Since 1- Phenyl ethyl free radical has a trigonal planar geometry so it is a planar molecule which has two faces and hence the radical recombination with bromine free radical can occur with either of the two faces available.
Kindly refer the attachments for structure as well as the mechanism of the reaction.
So two isomers which are enantiomers are produced are obtained.
