Answer:
See explanation and images attached
Explanation:
We know that the cis isomer has more heat of hydrogenation since it is less stable than the trans isomer. Since the hydrogenation of both compounds yields the same product and the hydroboration/oxidation both give a primary alcohol, they are geometric isomers and Y is the trans isomer (Image 2).
For the compound C8H12, the compound in question must be 1,5- cyclooctadiene since two moles of the same aldehyde was obtained after ozonolysis and reaction with two equivalents of hydrogen gives cyclooctane (Image 1).
Answer:
a) +640 kJ/mol or +1.06x10⁻¹⁸ J
b) +276 kJ/mol
Explanation:
To dissociate the molecule, the bond must be broken, thus, it's necessary energy equal to the energy of the bond, which can be calculated by:
E = (Q1*Q2)/(4*π*ε*r)
Where Q is the charge of the ions, ε is a constant (8.854x10⁻¹²C²J ⁻¹ m⁻¹), and r is the bond length. Each one of the ions has a charge equal to 1. The elementary charge is 1.602x10⁻¹⁹C, which will be the charge of them.
1 mol has 6.022x10²³ molecules (Avogadros' number), so the energy of 1 mol is the energy of 1 molecule multiplied by it:
E = 6.022x10²³ *(1.602x10⁻¹⁹)²/(4π*8.854x10⁻¹²*2.17x10⁻¹⁰)
E = +640113 J/mol
E = +640 kJ/mol
Or at 1 molecule: E =640/6.022x10²³ = +1.06x10⁻²¹ kJ = +1.06x10⁻¹⁸ J
b) The energy variation to dissociate the molecule at its neutral atoms is the energy of dissociation less the difference of the ionization energy of K and the electron affinity of F (EA):
498 = 640 - (418 - EA)
640 -418 + EA = 498
222 + EA = 498
EA = +276 kJ/mol
Answer:
a) The rocks have more mass, and therefore contain more matter, than the
feathers.
Explanation:
Answer:
, Kp = 0.08967
, Kp = 2.3×10³⁰
Explanation:
The relation between Kp and Kc is given below:
Where,
Kp is the pressure equilibrium constant
Kc is the molar equilibrium constant
R is gas constant
T is the temperature in Kelvins
Δn = (No. of moles of gaseous products)-(No. of moles of gaseous reactants)
For the first equilibrium reaction:
Given: Kc = 2.2
Temperature = 299 K
R = 0.082057 L atm.mol⁻¹K⁻¹
Δn = (2)-(2+1) = -1
Thus, Kp is:
<u>Kp = 0.08967 </u>
For the second equilibrium reaction:
Given: Kc = 2.3×10³⁰
Temperature = 299 K
R = 0.082057 L atm.mol⁻¹K⁻¹
Δn = (2)-(2) = 0
Thus, Kp is:
<u>Kp = 2.3×10³⁰</u>
There is currently no way to reliably predict when an earthquake will happen, its strength or length. Earthquakes can vary in their magnitude, the size of the earthquake at its source, and length, lasting from seconds to minutes.
Research has shown, that shaking of an earthquake displays a characteristic pattern. After the first tremors start, building up in intensity, a peak is reached, followed by a fading shaking. Large and small earthquakes start the same way, but there is no way to say when the peak, the maximal magnitude of the quake, is reached.
