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Genrish500 [490]
3 years ago
13

The activation energy for the reaction no2(g)+co(g)⟶no(g)+co2(g) is ea = 100 kj/mol and the change in enthalpy for the reaction

is δh = -375 kj/mol . what is the activation energy for the reverse reaction? express your answer with the appropriate units.
Chemistry
1 answer:
ladessa [460]3 years ago
7 0
<span>Answer: The activation energy for the reverse reaction is equal to the sum of the absolute value of DH + Ea(forward) or 275 kJ + 125 kJ = 400 kJ If you just sketch an energy diagram showing the activation energy and Delta H for the reaction, it should be apparent why this is the case.</span>
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How can you determine which bond in a structure is more polar without using an electronegativity table?
UkoKoshka [18]
To know this you pretty much do have to kind of memorize a few electronegativities. I don't recall ever getting a table of electronegativities on an exam.
From the structure, you have:

I remember the following electronegativities most because they are fairly patterned:
EN
H
=
2.1
EN
C
=
2.5
EN
N
=
3.0
EN
O
=
3.5
EN
F
=
4.0
EN
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~
0.5
. I believe Pauling made it that way when he determined electronegativities in the '30s.
Δ
EN
C
−
Cl
=
1.0
Δ
EN
C
−
H
=
0.4
Δ
EN
C
−
C
=
0.0
Δ
EN
C
−
O
=
1.0
Δ
EN
O
−
H
=
1.4
So naturally, with the greatest electronegativity difference of
4.0
−
2.5
=
1.5
, the
C
−
F
bond is most polar, i.e. that bond's electron distribution is the most drawn towards the more electronegative compound as compared to the rest.
When the electron distribution is polarized and drawn towards a more electronegative atom, the less electronegative atom has to move inwards because its nucleus was previously favorably attracted to the electrons from the other atom.
That means generally, the greater the electronegativity difference between two atoms is, the shorter you can expect the bond to be, insofar as the electronegative atom is the same size as another comparable electronegative atom.
However, examining actual data, we would see that on average, in conditions without other bond polarizations occuring:
r
C
−
Cl
≈
177 pm
r
C
−
C
≈
154 pm
r
C
−
O
≈
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r
C
−
F
≈
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r
C
−
H
≈
109 pm
r
O
−
H
≈
96 pm
So it is not necessarily the least electronegativity difference that gives the longest bond.
Therefore, you cannot simply consider electronegativity. Examining the radii of the atoms, you should notice that chlorine is the biggest atom in the compound.
r
Cl
≈
79 pm
r
C
≈
70 pm
r
H
≈
53 pm
r
O
≈
60 pm
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C
−
C
, what would have to hold true is that:
The
C
−
F
bond polarization makes the carbon more electropositive (which is true).
The now more electropositive carbon wishes to attract bonding pairs from chlorine closer, thereby shortening the
C
−
Cl
bond, and potentially the
C
−
H
bond (which is probably true).
The shortening of the
C
−
Cl
bond is somehow enough to be shorter than the
C
−
C
bond (this is debatable).
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