Answer:
more electron deficient
Explanation:
The nitro group is an electron withdrawing group. It withdraws electrons from the pyridine ring by resonance.
This electron withdrawal by resonance makes the pyridine ring less electron rich or more electron deficient.
Hence, the nitro group makes the pyrinde ring more electron deficient
Answer:

Explanation:
For a first order reaction the rate law is:
![v=\frac{-d[A]}{[A]}=k[A]](https://tex.z-dn.net/?f=v%3D%5Cfrac%7B-d%5BA%5D%7D%7B%5BA%5D%7D%3Dk%5BA%5D)
Integranting both sides of the equation we get:
![\int\limits^a_b {\frac{d[A]}{[A]}} \, dx =-k\int\limits^t_0 {} \, dt](https://tex.z-dn.net/?f=%5Cint%5Climits%5Ea_b%20%7B%5Cfrac%7Bd%5BA%5D%7D%7B%5BA%5D%7D%7D%20%5C%2C%20dx%20%3D-k%5Cint%5Climits%5Et_0%20%7B%7D%20%5C%2C%20dt)
where "a" stands for [A] (molar concentration of a given reagent) and "b" is {A]0 (initial molar concentration of a given reagent), "t" is the time in seconds.
From that integral we get the integrated rate law:
![ln\frac{[A]}{[A]_{0} } =-kt](https://tex.z-dn.net/?f=ln%5Cfrac%7B%5BA%5D%7D%7B%5BA%5D_%7B0%7D%20%7D%20%3D-kt)
![[A]=[A]_{0}e^{-kt}](https://tex.z-dn.net/?f=%5BA%5D%3D%5BA%5D_%7B0%7De%5E%7B-kt%7D)
![ln[A]=ln[A]_{0} -kt](https://tex.z-dn.net/?f=ln%5BA%5D%3Dln%5BA%5D_%7B0%7D%20-kt)
![k=\frac{ln[A]_{0}-ln[A]}{t}](https://tex.z-dn.net/?f=k%3D%5Cfrac%7Bln%5BA%5D_%7B0%7D-ln%5BA%5D%7D%7Bt%7D)
therefore k is

Answer:
it will option B ,hope it helps
The answer is D.timber good luck