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Liono4ka [1.6K]
3 years ago
5

What masses of iron(iii) oxide and aluminum must be used to produce 15.0 g iron? what is the maximum mass of aluminum oxide that

could be produced?
Chemistry
1 answer:
defon3 years ago
6 0
1) Chemical reaction:

Fe2O3 + 2Al ---> Al2O3 + 2Fe

2) molar ratios

1 mol Fe2O3 : 2Al : 1 mol Al2O3 : 2 mol Fe

3) Convert 15.0 g of iron into moles

atomic mass Fe = 55.8 g/mol

moles = mass in grams / atomic mass = 15.0 g / 55.8 g/mol = 0.269 mol

4) Use proportions to determine the moles of Fe2O3, Al, and Al2O3

a) 1mol Fe2O3 / 2 mol Fe = x / 0.269 mol Fe

x =

=> x = 0.269 mol Fe * 1 mol Fe2O3 / 2 mol Fe = 0.134 mol Fe2O3

b) 2 mol Al / 2 mol Fe = x / 0.269 mol Fe

=> x = 0.269 mol Al

c) 2 mol Fe / 1 mol Al2O3 = 0.269 mol Fe / x

=> x = 0.269 mol Fe * 1 mol Al2O3 / 2 mol Fe

x = 0.134 mol Al2O3

5) Convert moles to grams

a) Fe2O3

molar mass Fe2O3 = 2* 55.8 g/mol + 3*16g/mol = 159.6 g/mol

mass = molar mass * number of moles

mass = 159.6 g/mol * 0.134 mol = 21.4 g

b) Al

atomic mass = 27.0 g/mol

mass = number of moles * atomic mass = 0.269 mol * 27.0 g/mol = 7.26 g

c) Al2O3

molar mass = 2 * 27.0 g/mol + 3*16.0 g/mol = 102.0g/mol

mass Al2O3 = numer of moles * molar mass = 0.134 mol * 102.0 g/mol = 13.7 g

Answers:

21.4 g Fe2O3

7.26 g Al

13.7 g Al2O3
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The question is incomplete, the complete question is:

When 177. g of alanine (C_3H_7NO_2) are dissolved in 800.0 g of a certain mystery liquid X, the freezing point of the solution is 5.9^oC lower than the freezing point of pure X. On the other hand, when 177.0 g of potassium bromide are dissolved in the same mass of X, the freezing point of the solution is 7.2^oC lower than the freezing point of pure X. Calculate the van't Hoff factor for potassium bromide in X.

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<u>Explanation:</u>

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\Delta T_f=i\times K_f\times \frac{m_{solute}\times 1000}{M_{solute}\times w_{solvent}\text{(in g)}} ......(1)

  • <u>When alanine is dissolved in mystery liquid X:</u>

\Delta T_f=5.9^oC

i = Vant Hoff factor = 1 (for non-electrolytes)

K_f = freezing point depression constant

m_{solute} = Given mass of solute (alanine) = 177. g

M_{solute} = Molar mass of solute (alanine) = 89 g/mol

w_{solvent} = Mass of solvent = 800.0 g

Putting values in equation 1, we get:

5.9=1\times K_f\times \frac{177\times 1000}{89\times 800}\\\\K_f=\frac{5.9\times 89\times 800}{1\times 177\times 1000}\\\\K_f=2.37^oC/m

  • <u>When KBr is dissolved in mystery liquid X:</u>

\Delta T_f=7.2^oC

i = Vant Hoff factor = ?

K_f = freezing point depression constant = 2.37^oC/m

m_{solute} = Given mass of solute (KBr) = 177. g

M_{solute} = Molar mass of solute (KBr) = 119 g/mol

w_{solvent} = Mass of solvent = 800.0 g

Putting values in equation 1, we get:

7.2=i\times 2.37\times \frac{177\times 1000}{119\times 800}\\\\i=\frac{7.2\times 119\times 800}{2.37\times 177\times 1000}\\\\i=1.63

Hence, the van't Hoff factor for potassium bromide in X is 1.63

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