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Anna11 [10]
3 years ago
13

What will be the final temperature of the solution in a coffee cup calorimeter if a 50.00 mL sample of 0.250 M HCl(aq) is added

to a 50.00 mL sample of 0.250 NaOH(aq). The initial temperature is 19.50 °C and the Hrxn is −57.2 kJ/mol NaOH. (assume the density of the solution is 1.00 g/mL and the specific heat of the solution is 4.18 J/g∙°C)
Chemistry
1 answer:
padilas [110]3 years ago
5 0

Answer:

21.21°C will be the final temperature of the solution in a coffee cup calorimeter.

Explanation:

HCl+NaOH\rightarrow H_2O+NaCl

\Delta H = enthalpy change = -57.2 kJ/mol of NaOH

Moles of sodium hydroxide = n

Molarity of the NaOH = 0.250 M

Volume of NaOH solution = V = 50.00 mL = 0.050 L

n=Molarity\times V=0.250 M\times 0.050 L= 0.0125 mol

Moles of HCl = n'

Molarity of the HCl= 0.250 M

Volume of HCl solution = V' = 50.00 mL = 0.050 L

n'=Molarity\times V=0.250 M\times 0.050 L= 0.0125 mol

Since 1 mole of Hcl reacts with 1 mole of NaoH. Then 0.0125 mole of HCl will react with 0.0125 mole of NaOH.

The enthalpy change during the reaction.

\Delta H=-\frac{q}{n}

q=\Delta H\times n=-57.2 kJ/mol \times 0.0125 mol= -0.715 kJ=-715 J

q = heat released on reaction= -715 J

now, we calculate the heat gained by the solution.:

Q= -q = -(-715 J) = 715 J

m = mass of the solution = ?

Volume of the solution formed by mixing, v = 50.00 ml + 50.00 mL = 100.00 mL

Density of the solution = density of water = d = 1 g/mL

mass=density\times volume=d\times v=1 g/ml \times 100.00 ml=100 g

m = 100 g

q = heat gained = ?

c = specific heat = 4.18 J/^oC

T_{f} = final temperature = ?

T_{i} = initial temperature = 19.50^oC

Q=mc\times (T_{f}-T_{i})

Now put all the given values in the above formula, we get:

715 J=100 g\times 4.18J/^oC\times (T_f-19.50)^oC

T_f=21.21 ^oC

21.21°C will be the final temperature of the solution in a coffee cup calorimeter.

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1.58×10E18

Explanation:

Since we have the reduction potentials we could make decisions regarding which one will be the anode or cathode. Evidently, bromine having the more positive reduction potential will be the cathode while the iodine will be the anode.

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A sample containing 16.93 metal pellets is poured into a graduated cylinder containing 11.2 of water, causing the water level in
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<h3>The answer is 1.99 g/mL</h3>

Explanation:

The density of a substance can be found by using the formula

density =  \frac{mass}{volume} \\

From the question

mass = 16.93 g

volume = final volume of water - initial volume of water

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We have

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We have the final answer as

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Hope this helps you

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Suppose 0.035 moles of HCl is dissolved in enough water to produce 750 mL of solution. What is the pH
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Answer:

pH = 1.33

Explanation:

Because HCl is a strong acid, each mole of HCl will completely dissociate into H⁺ and Cl⁻ species.

Now we calculate the molar concentration (molarity) of H⁺:

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(750 mL ⇒ 750 / 1000 = 0.750 L)

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Then we calculate the pH of the solution:

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