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rodikova [14]
3 years ago
5

Consider a buffer solution containing CH3COOH and CH3COO-, with an equilibrium represented by: CH3COOH(aq) + H2O (l) ←----→ H3O+

(aq) + CH3COO- (aq) Describe what occurs if a strong acid such as HNO3 is added to the system, including an explanation of the direction of the equilibrium shift. Describe what occurs if a strong base such as KOH is added, including an explanation of the direction of the equilibrium shift.
Chemistry
1 answer:
Irina-Kira [14]3 years ago
5 0

Answer:

Here's what I get.

Explanation:

(a) The buffer equilibrium

The equation for the buffer equilibrium is

\rm CH_{3}COOH(aq) + H$_{2}$O(l) $\, \rightleftharpoons \,$ CH$_{3}$COO$^{-}$(aq) + H$_{3}$O$^{+}$(aq)

(b) Addition of acid

If you add a strong acid like HNO₃, you are increasing the concentration of hydronium ion.

Per Le Châtelier's Principle, the system will respond in such a way as to decrease the concentration of hydronium ion.

The position of equilibrium will shift to the left.

(c) Addition of base.

If you add a strong base like KOH, The hydroxide ions will react with the hydronium ions to form water.

The concentration of hydronium ions will decrease.

Per Le Châtelier's Principle, the system will respond in such a way as to increase the concentration of hydronium ions.

The position of equilibrium will shift to the right.

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Titanium is a transition metal used in many alloys because it is extremely strong and lightweight. Titanium tetrachloride (TiCl4
vova2212 [387]

Answer:

a) 226.6 grams of Cl₂

b) 19.2 grams of C

c) 303.2 grams of TiCl₄ and 70.4 grams of CO₂

Explanation:

The balanced chemical reaction is the following:

TiO₂(s) + C(s) + 2 Cl₂(g) → TiCl₄(s) + CO₂(g)

(a) What mass of Cl₂ gas is needed to react with 1.60 mol TiO₂?

From the chemical equation, 1 mol of TiO₂ reacts with 2 moles of Cl₂. So, the stoichiometric ratio is 2 mol Cl₂/1 mol TiO₂. We multiply this ratio by the moles of TiO₂ we have to calculate the moles of Cl₂ we need:

1.60 mol TiO₂ x 2 mol Cl₂/1 mol TiO₂ = 3.2 mol Cl₂

Now, we convert from moles to mass by using the molecular weight (MW) of Cl₂:

MW(Cl₂) = 35.4 g/mol x 2 = 70.8 g/mol

mass of Cl₂= 3.2 mol x 70.8 g/mol = 226.6 g

<em>Therefore, 226.6 grams of Cl₂ are needed to react with 1.6 mol of TiO₂. </em>

(b) What mass of C is needed to react with 1.60 mol of TiO₂?

From the chemical equation, 1 mol of TiO₂ reacts with 1 moles of C(s). So, the stoichiometric ratio is 1 mol C/1 mol TiO₂. We multiply this ratio by the moles of TiO₂ we have to calculate the moles of C(s) we need:

1.60 mol TiO₂ x 1 mol C(s)/1 mol TiO₂ = 1.60 mol C(s)

So, we convert the moles of C(s) to grams as follows:

MW(C) = 12 g/mol

1.60 mol x 12 g/mol = 19.2 g C(s)

<em>Therefore, a mass of 19.2 grams of C is needed to react with 1.60 mol of TiO₂. </em>

(c) What is the mass of all the products formed by reaction with 1.60 mol of TiO₂?

From the chemical equation, we can notice that 1 mol of TiO₂ produces 1 mol of TiCl₄ and 1 mol of CO₂. So, from 1.60 moles of TiO₂, 1 mol of each product will be produced:

1 mol TiO₂/1 mol TiCl₄ ⇒ 1.60 mol TiO₂/1.60 mol TiCl₄

1 mol TiO₂/1 mol CO₂ ⇒ 1.60 mol TiO₂/1.60 mol CO₂

Finally, we convert the moles to grams by using the molecular weight of each compound:

MW(TiCl₄) = 47.9 g/mol Ti + (35.4 g/mol x 4 Cl) = 189.5 g/mol

1.60 mol x 189.5 g/mol = 303.2 g

MW(CO₂) = 12 g/mol C + (16 g/mol x 2 O) = 44 g/mol

1.60 mol x 44 g/mol = 70.4 g

<em>Therefore, from the reaction of 1.60 mol of TiO₂ are formed 303.2 grams of TiCl₄ and 70.4 grams of CO₂.</em>

3 0
3 years ago
What is the pH of a 8.7 x 10^-12 M OH- solution ? pH= ?
vivado [14]
PH=14-pOH

pOH=-lg[OH⁻]

pH=14+lg[OH⁻]

pH=14+lg(8.7*10⁻¹²)=14-11.06=2,94
5 0
3 years ago
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iogann1982 [59]

Answer:

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Explanation:

hope this helps :).

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What is the new volume of a balloon originally at 755 torr and 5.00 l is placed in a container in which the pressure is increase
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Answer is: volume will be 3.97 liters.

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p₁V₁ = p₂V₂.

p₁ = 755 torr.

V₁ = 5.00 l.

p₂ = 1.25 atm · 760 torr/atm.

p₂ = 950 torr.

755 torr · 5 l = 950 torr · V₂.

V₂ = 755 torr · 5 l / 950 torr.

V₂ =  3.97 l.

When pressure goes up, volume goes down.

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3 years ago
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