The rate equation is given as:
k = A e^(- Ea / RT)
Dividing state 1 and state 2:
k1/k2 = e^(- Ea / RT1) / e^(- Ea / RT2)
k1/k2 = e^[- Ea / RT1 - (- Ea / RT2)]
k1/k2 = e^[- Ea / RT1 + Ea / RT2)]
Taking the ln of both sides:
ln (k1/k2) = - Ea / RT1 + Ea / RT2
ln (k1/k2) = - Ea / R (1/T1 - 1/T2)
Since k2 = 4k1, therefore k1/k2 = ¼
ln (1/4) = [- (56,000 J/mol) / (8.314 J / mol K)] (1/273
K – 1/ T2)
2.058 x 10^-4 = 1/273 – 1/T2
T2 = 289.25 K
Answer : The value of
is 28.97 kJ/mol
Explanation :
To calculate
of the reaction, we use clausius claypron equation, which is:
![\ln(\frac{P_2}{P_1})=\frac{\Delta H_{vap}}{R}[\frac{1}{T_1}-\frac{1}{T_2}]](https://tex.z-dn.net/?f=%5Cln%28%5Cfrac%7BP_2%7D%7BP_1%7D%29%3D%5Cfrac%7B%5CDelta%20H_%7Bvap%7D%7D%7BR%7D%5B%5Cfrac%7B1%7D%7BT_1%7D-%5Cfrac%7B1%7D%7BT_2%7D%5D)
where,
= vapor pressure at temperature
= 462.7 mmHg
= vapor pressure at temperature
= 140.5 mmHg
= Enthalpy of vaporization = ?
R = Gas constant = 8.314 J/mol K
= initial temperature = ![-21.0^oC=[-21.0+273]K=252K](https://tex.z-dn.net/?f=-21.0%5EoC%3D%5B-21.0%2B273%5DK%3D252K)
= final temperature = ![45^oC=[-41.0+273]K=232K](https://tex.z-dn.net/?f=45%5EoC%3D%5B-41.0%2B273%5DK%3D232K)
Putting values in above equation, we get:
![\ln(\frac{140.5mmHg}{462.7mmHg})=\frac{\Delta H_{vap}}{8.314J/mol.K}[\frac{1}{252}-\frac{1}{232}]\\\\\Delta H_{vap}=28966.6J/mol=28.97kJ/mol](https://tex.z-dn.net/?f=%5Cln%28%5Cfrac%7B140.5mmHg%7D%7B462.7mmHg%7D%29%3D%5Cfrac%7B%5CDelta%20H_%7Bvap%7D%7D%7B8.314J%2Fmol.K%7D%5B%5Cfrac%7B1%7D%7B252%7D-%5Cfrac%7B1%7D%7B232%7D%5D%5C%5C%5C%5C%5CDelta%20H_%7Bvap%7D%3D28966.6J%2Fmol%3D28.97kJ%2Fmol)
Therefore, the value of
is 28.97 kJ/mol
Answer:
B.spiderman
Explanation:
DNA has been transferred to another species. Spiderman became Spiderman when DNA from a spider combined with a human.
Answer:
Low energy waves have <u>a long wavelength.</u>
Explanation:
Energy of wave is directly related to the frequency while it is inversely proportional to the wavelength.
If any wave have high energy it will have high frequency and smaller wavelength.
If the wave have lower energy then it will have lower frequency and higher wavelength.
Mathematical relationship:
E = h. f
E = h. c/λ
E= energy
h = planck's constant
f = frequency
c = speed of light
λ = wavelength
Do you have the picture of the data?