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gogolik [260]
2 years ago
5

a sample of an oxide of iron was reduced to iron by heating with hydrogen. the mass of iron obtained was 4.35g and mass of water

is 1.86g. deduce the equation for the reaction occurred.​
Chemistry
1 answer:
Hitman42 [59]2 years ago
5 0

Answer:

FeO(s) + H2(g)→ Fe(s) + H2O(g)

Explanation:

Moles of Iron will be = 4.35 g/55.845 g/mol

                                  = 0.0786 moles

Moles of water = 1.86 g/18 g/mol

                         = 0.103 moles

The mole ratio of Iron to water

= 0.0786 : 0.103

= 1   :  1.3

= 1 : 1

Therefore, the equation for the reaction is;

FeO(s) + H2(g)→ Fe(s) + H2O(g)

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Make sure that you understand what they are asking you from this question, as it can be confusing, but the solution is quite simple. They are stating that they want you to calculate the final concentration of 6.0M HCl once a dilution has been made from 2.0 mL to 500.0 mL. They have given us three values, the initial concentration, initial volume and the final volume. So, we are able to employ the following equation:

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(a) if a sample containing 2.00 ml of nitroglycerin is detonated, how many total moles of gas are produced? (b) if each mole of
gregori [183]
Detonation of nitroglycerin: 

4C_3H_5N_3O_9  ------\ \textgreater \  12CO_2+6N_2+O_2+H_2O

<span>Mass nitroglycerin = 2.00 mL x 1.592 g/mL = 3.184 g 
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Moles = mass / molar mass = 3.184<span> g/ 227.0872 g/mol = 0.01402
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the ratio between nitroglycerin and Carbon dioxide is 4 : 12 
So, moles CO2 = 0.01402 x 12 / 4 =0.0420

the ratio between nitroglycerin and N2 is 4 : 6 
moles N2 = 0.01402 x 6 / 4 =0.0841

<span>the ratio between nitroglycerin and O2 is 4 : 1 </span>
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<span>the ratio between nitroglycerin and water is 4 : 1 </span>
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total moles = 0.0420 + 0.0841 + 0.0035 + 0.005258 = 0.130758

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2 years ago
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padilas [110]
Single replacement because only one letter is being switched out in the reaction
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Be sure to answer all parts. Styrene is produced by catalytic dehydrogenation of ethylbenzene at high temperature in the presenc
svlad2 [7]

Answer:

a) ΔHºrxn = 116.3 kJ, ΔGºrxn = 82.8 kJ,  ΔSºrxn =  0.113 kJ/K

b) At 753.55 ºC or higher

c )ΔG =  1.8 x 10⁴ J

    K = 8.2 x 10⁻²

Explanation:

a)                                 C6H5−CH2CH3  ⇒  C6H5−CH=CH2  + H₂

ΔHf kJ/mol                    -12.5                           103.8                      0

ΔGºf kJ/K                        119.7                         202.5                      0

Sº J/mol                          255                          238                      130.6*

Note: This value was not given in our question, but is necessary and can be found in standard handbooks.

Using Hess law to calculate  ΔHºrxn we have

ΔHºrxn  = ΔHfº C6H5−CH=CH2 +  ΔHfº H₂ - ΔHºfC6H5−CH2CH3

ΔHºrxn =     103.8 kJ + 0 kJ  - (-12.5 kJ)

ΔHºrxn = 116.3 kJ

Similarly,

ΔGrxn = ΔGºf C6H5−CH=CH2 +  ΔGºfH₂ - ΔGºfC6H5CH2CH3

ΔGºrxn=   202.5 kJ + 0 kJ - 119.7 kJ  = 82.8 kJ

ΔSºrxn = 238 J/mol + 130.6 J/mol -255 J/K = 113.6 J/K = 0.113 kJ/K

b) The temperature at which the reaction is spontaneous or feasible occurs when ΔG becomes negative and using

ΔGrxn =  ΔHrxn -TΔS

we see that will happen when the term  TΔS  becomes greater than ΔHrxn since ΔS  is positive  , and so to sollve for T we will make ΔGrxn equal to zero and solve for T. Notice here we will make the assumption that  ΔºHrxn and ΔSºrxn remain constant at the higher temperature  and will equal the values previously calculated for them. Although this assumption is not entirely correct, it can be used.

0 = 116 kJ -T (0.113 kJ/K)

T = 1026.5 K  =  (1026.55 - 273 ) ºC = 753.55 ºC

c) Again we will use

                       ΔGrxn =  ΔHrxn -TΔS

to calculate ΔGrxn   with the assumption that ΔHº and ΔSºremain constant.

ΔG =  116.3 kJ - (600+273 K) x 0.113 kJ/K =  116.3 kJ - 873 K x 0.113 kJ/K

ΔG =  116.3 kJ - 98.6 kJ =  17.65 kJ = 1.8 x 10⁴ J ( Note the kJ are converted to J to necessary for the next part of the problem )

Now for solving for K, the equation to use is

ΔG = -RTlnK and solve for K

- ΔG / RT = lnK  ∴ K = exp (- ΔG / RT)

K = exp ( - 1.8 x 10⁴ J /( 8.314 J/K  x 873 K)) = 8.2 x 10⁻²

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Answer:

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Explanation:

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