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Paul [167]
3 years ago
10

What is the freezing point of an aqueous solution made by dissolving 0.118 mole of MgCl2 in 100.0 g of water? Kf = 1.86 oC/m

Chemistry
1 answer:
Sauron [17]3 years ago
8 0

Answer:

Freezing point of solution is -4.39°C

Explanation:

Freezing point depression's formula:

ΔT = Kf . m . i

ΔT = Freezing point of pure solvent - Freezing point of solution

0°C - X = 1.86°C/m . m . 2

i = Van't Hoff factor, ions dissolved in solution

MgCl₂ → Mg²⁺  + 2Cl⁻     i = 3  →  1 mol of Mg and 2 mol of chloride

Let's think the molality (mol/kg)

First of all, let's convert the mass of solvent from g to kg

100 g / 1000 = 0.1 kg

Molality (mol/kg) = 0.118 mol / 0.1 kg = 1.18 m

0°C - X = 1.86°C/m . 1.18 m . 2

X = - 4.39°C

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<em>Full question: Assume no volume change.  If you formed 0.0910 atm of gas, what is the percent yield?</em>

<em />

The reaction that is occurring is:

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Using ideal gas law, we can determine the moles of hydrogen formed. Thus, we can find percent yield:

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For a complete reaction of the 0.084 moles of HBr you need:

0.084mol HBr * (1 mole Ni / 3 moles HBr) = 0.028 moles of Ni.

As there are just 0.01738 moles of Ni, the Ni is limiting reactant. Assuming a theoretical yield, moles of H₂ produced are:

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PV = nRT

PV/RT = n

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<em />

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