When ammonium chloride dissolves in water, the solution becomes colder. (a) is the solution process exothermic or endothermic? (
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Answer:
All of the above.
Explanation:
In positive deviation from Raoult's Law occur when the vapour pressure of components is greater than what is expected value in Raoult's law.
When a solution is non ideal then it shows positive or negative deviation.
Let two solutions A and B to form non- ideal solutions.let the vapour pressure of component A is and vapour pressure of component B is
.
= Vapour pressure of component A in pure form
= Vapour pressure of component B in pure form
=Mole fraction of component A
=Mole fraction of component B
The interaction between A- B is less than the interaction A- A and B-B interaction.Therefore, the escaping tendency of liquid molecules in mixture is greater than the escaping tendency in pure form.Hence, the vapour pressure of a mixture is greater than the initial value of vapour pressure.
,
Therefore,
Therefore, the enthalpy of mixing is greater than zero and change in volume is greater than zero.
Hence, option a,b,c and d are true.
This question is describing the following chemical reaction at equilibrium:
And provides the relative amounts of both A and B at 25 °C and 75 °C, this means the equilibrium expressions and equilibrium constants can be written as:
Thus, by recalling the Van't Hoff's equation, we can write:
Hence, we solve for the enthalpy change as follows:
Finally, we plug in the numbers to obtain:
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