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QveST [7]
3 years ago
13

Use molecular orbital theory to determine whether f22+ is paramagnetic or diamagnetic.

Chemistry
2 answers:
Alexxandr [17]3 years ago
7 0

We have to know whether F₂²⁺ is paramagnetic or diamagnetic.

F₂²⁺ is paramagnetic.

If number of unpaired electron in any species is equal to zero, the species is diamagnetic and the species contains unpaired electrons, then the species is paramagnetic.

The magnetic property can be explained using molecular orbital theory.

Total number of electron present in   F₂²⁺ is equal to 16 (i.e, 9+9-2). From the molecular orbital electronic configuration, number of electrons present in pi orbitals present is equal to 2.

So,  F₂²⁺ is paramagnetic.

Fynjy0 [20]3 years ago
4 0

Answer : F_2^{2+} is paramagnetic.

Explanation :

According to the molecular orbital theory, the general molecular orbital configuration will be,

(\sigma_{1s}),(\sigma_{1s}^*),(\sigma_{2s}),(\sigma_{2s}^*),[(\pi_{2p_x})=(\pi_{2p_y})],(\sigma_{2p_z}),[(\pi_{2p_x}^*)=(\pi_{2p_y}^*)],(\sigma_{2p_z}^*)

As there are 9 electrons present in fluorine.

The number of electrons present in F_2^{2+} molecule = 2(9) - 2 = 16

The molecular orbital configuration of F_2^{2+} molecule will be,

(\sigma_{1s})^2,(\sigma_{1s}^*)^2,(\sigma_{2s})^2,(\sigma_{2s}^*)^2,(\sigma_{2p_z})^2,[(\pi_{2p_x})^2=(\pi_{2p_y})^2],[(\pi_{2p_x}^*)^1=(\pi_{2p_y}^*)^1],(\sigma_{2p_z}^*)^0

Paramagnetic compounds : They have unpaired electrons.

Diamagnetic compounds : They have no unpaired electrons that means all are paired.

The number of unpaired electron in molecule is, 2. So, this is paramagnetic. That means, more the number of unpaired electrons, more paramagnetic.

Thus, is paramagnetic.

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The decomposition of dinitrogen pentoxide, N2O5, to NO2 and O2 is a first-order reaction. At 60°C, the rate constant is 2.8 × 10
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Answer:

a. 113 min

Explanation:

Considering the equilibrium:-

                   2N₂O₅ ⇔ 4NO₂ + O₂

At t = 0        125 kPa

At t = teq     125 - 2x      4x        x

Thus, total pressure = 125 - 2x + 4x + x = 125 - 3x

125 - 3x = 176 kPa

x = 17 kPa

Remaining pressure of N₂O₅ = 125 - 2*17 kPa = 91 kPa

Using integrated rate law for first order kinetics as:

[A_t]=[A_0]e^{-kt}

Where,  

[A_t] is the concentration at time t

[A_0] is the initial concentration

Given that:

The rate constant, k = 2.8\times 10^{-3} min⁻¹

Initial concentration [A_0] = 125 kPa

Final concentration [A_t] = 91 kPa

Time = ?

Applying in the above equation, we get that:-

91=125e^{-2.8\times 10^{-3}\times t}

125e^{-2.8\times \:10^{-3}t}=91

-2.8\times \:10^{-3}t=\ln \left(\frac{91}{125}\right)

t=113\ min

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2 years ago
Which of these is a reason why nuclear power is important?
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Answer:

C Fossil fuels will run out soon

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easy

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In physics and chemistry, the law of conservation of energy states that the total energy of an isolated system remains constant; it is said to be conserved over time. This law means that energy can neither be created nor destroyed; rather, it can only be transformed or transferred from one form to another.

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The heat will flow from copper to aluminum because Cu is at higher temperature. The heat liberated is -7.60kJ

When two metals at different temperatures are kept in contact, heat flows from hotter metal to colder metal until thermal equilibrium is reached.

Here Copper is at a temperature of 60 degree Celsius and aluminum is at 40 degree Celsius. Thus, heat will flow from Cu to Al.

In order to calculate the amount of heat liberated following calculations are required.

m1=262 g

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T2=11.8 oC

The heat liberated can be expressed as follows:

Q=mCp(T2-T1)

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