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Naddik [55]
4 years ago
7

This ether, C4H8O, can be produced by slow distillation from an acidic solution of 1,4-butanediol, HOCH2CH2CH2CH2OH. It gives a

negative test for C-C double bonds. Propose a structure for this compound.

Chemistry
1 answer:
horrorfan [7]4 years ago
6 0

Answer:

Tetrahydrofuran

Explanation:

Since the compound tested negative for C-C double bond, it must be a cyclic ether. Cyclic ethers have the oxygen atom attached to a ring. It is important to note that in a cyclic compound, one carbon atom is only bonded to two hydrogen atoms. Hence there are four carbon atoms in the compound, eight hydrogen atoms and one oxygen atom. This corresponds to the structure of tetrahydrofuran. Its structure is shown in the image attached.

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A compound consists of only one type of element?
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A compound can easily be split up into its different elements.

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Nitrogen dioxide is one of the many oxides of nitrogen (often collectively called "NOx") that are of interest to atmospheric che
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Partial pressure of dinitrogen tetroxide after equilibrium is reached the second time is 0.82 atm.

Explanation:

2NO_2(g)\rightleftharpoons N_2O_4(g)

Initially

3.0 atm                 0

At equilibrium

(3.0-2p)                 p

Equilibrium partial pressure of NO_2=2.1atm=3.0-2p

p = 0.45 atm

The value of equilibrium constant wil be given by :

K_p=\frac{p_{N_2O_4}}{(p_{NO_2})^2}=\frac{p}{(3.0-2p)^2}

K_p=\frac{0.45}{(2.1)^2}=0.10

After addition of 1.5 atm of nitrogen dioxide gas equilibrium reestablishes it self :

2NO_2(g)\rightleftharpoons N_2O_4(g)

After adding 1.5 atm of NO_2:

(2.1+1.5) atm                0.45 atm

At second equilibrium:'

(3.6-2P)                     (0.45+P)

The expression of equilibrium can be written as:

K_p=\frac{p'_{N_2O_4}}{(p'_{NO_2})^2}

0.10=\frac{(0.45+P)}{(3.6-2P)^2}

Solving for P:

P = 0.37 atm

Partial pressure of dinitrogen tetroxide after equilibrium is reached the second time:

= (0.45+P) atm = (0.45 + 0.37 )atm = 0.82 atm

Partial pressure of dinitrogen tetroxide after equilibrium is reached the second time is 0.82 atm.

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