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Aneli [31]
3 years ago
5

"solid potassium iodide decomposes into iodine gas and solid potassium. Write a a balanced chemical equation for this reaction"

Chemistry
1 answer:
wel3 years ago
3 0
KI (s)  ----\ \textgreater \     K(s)  + I_2 (g)

Now, balance the equation:

2KI (s)  ----\ \textgreater \     2K(s)  + I_2 (g)

I_2 in gaseous state exist as a diatomic molecule.
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A 25.0 mL solution of 0.100 M CH3COOH is titrated with a 0.200 M KOH solution. Calculate the pH after the following additions of
zaharov [31]

Answer:

a) pH = 2.88

b) pH = 4.598

c) pH = 5.503

d) pH = 8.788

e) pH = 12.097

Explanation:

  • CH3COOH ↔ CH3COO-  +  H3O+

∴ Ka = 1.75 E-5 = [H3O+]*[CH3COO-] / [CH3COOH]

a) 0.0 mL KOH:

mass balance:

⇒ <em>C</em> CH3COOH = [CH3COOH] + [CH3COO-] = 0.100 M

charge balance:

⇒ [H3O+] = [CH3COO-]

⇒ 1.75 E-5 = [H3O+]²/(0.100 - [H3O+])

⇒ [H3O+]² + 1.75 E-5[H3O+] - 1.75 E-6 = 0

⇒ [H3O+] = 1.314 E.3 M

∴ pH = - Log [H3O+]

⇒ pH = 2.88

b) 5.0 mL KOH:

  • CH3COOH + KOH ↔ CH3COONa + H2O

∴ <em>C </em>CH3COOH = ((0.025)(0.100) - (5 E-3)(0.200))/(0.025+5 E-3)

⇒ <em>C</em> CH3COOH = 0.05 M

∴ <em>C</em> KOH = ((5 E-3)(0,200))/(0.025+5 E-3) = 0.033 M

mass balance:

⇒ <em>C</em> CH3COOH + <em>C</em> KOH = [CH3COOH] + [CH3COO-] = 0.05 + 0.033 = 0.083 M

charge balance:

⇒ [H3O+] + [K+] = [CH3COO-]

⇒ [CH3COO-] = [H3O+] + 0.033

⇒ 1.75 E-5 = ([H3O+]*([H3O+] + 0.033))/(0.083 - ([H3O+] + 0.033))

⇒ 1.75 E-3 = ([H3O+]² + 0.033[H3O+])/(0.05 - [H3O+])

⇒ 8.75 E-7 - 1.75 E-5[H3O+] = [H3O+]² + 0.033[H3O+]

⇒ [H3O+]² +0.03302[H3O+] - 8.75 E-7 = 0

⇒ [H3O+] = 2.523 E-5 M

⇒ pH = 4.598

equivalent point:

  • (<em>C</em>*V)acid = (<em>C</em>*V)base

⇒ (0.100 M)*(0.025 L) = (0.200 M)( Vbase)

⇒ Vbase = 0.0125L = 12.5 mL

c) 10.0 mL KOH:

∴ <em>C</em> CH3COOH = 0.0143 M

∴ <em>C</em> KOH =  0.057 M

as in the previous point, starting from the mass and charge balances, we obtain:

⇒ [H3O+] = 3.1386 E-6 M

⇒ pH = 5.503

d) 12.5 mL KOH:

at the equivalence point, there is complete salt formation, then the pH is calculated through the salt:

  • CH3COO- + H2O ↔ CH3COOH - OH-

∴ Kw/Ka = 1 E-14/1.75 E-5 = 5.714 E-10 = [CH3COOH]*[OH-]/[CH3COO-]

∴ [CH3COO-] = (0.025)(0.100))/(0.025+0.0125) = 0.066 M

mass balance:

⇒ 0.066 = [CH3COOH] + [CH3COO-]..........(1)

charge balance:

⇒ [K+] = [OH-] + [CH3COO-] = 0.066 M.........(2)

∴ [K+] = <em>C</em> CH3COO- = 0.066 M

(1) = (2):

⇒ [OH-] = [CH3COOH].......(3)

⇒ 5.714 E-10 = [OH-]² / (0.066 - [OH-])

⇒ [OH-]² + 5.714 E-10[OH-] - 3.7712 E-11 = 0

⇒ [OH-] = 6.1408 e-6 m

⇒ pOH = 5.212

⇒ pH = 14 - pOH = 8.788

d) 15.0 mL KOH:

after the equivalence point there is salt and excess base (OH-); ph is calculated from excess base:

⇒ <em>C</em> KOH = ((0.015)(0.200) - (0.025)(0.100)) / (0.025 + 0.015) = 0.0125 M

⇒ [OH-] ≅ <em>C</em> KOH = 0.0125 M

⇒ pOH = 1.903

⇒ pH = 12.097

8 0
3 years ago
What would happen to a diver who does no exhale while surfacing from a 30 m dive?
sertanlavr [38]
Their lungs would try to expand to about 4 timed the normal volume which would force air into the various body tissues. this can cause a lung expansion injury and it could case air embolism. Air embolism is when air bubbles get trapped in blood vessels. This can lead to a blockage which will could be fatal.
6 0
3 years ago
Hey um i dont get this yall wont to help me out???
den301095 [7]
3. 9
20. 60 (1hour)
To get to 60 from 20 we multiply by three. 3 times 3 is 9.
A is true
B is true
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4 0
3 years ago
A. 6.07 x 10-15<br> How many significant figures are there in this equation
Harman [31]

Answer:

3

Explanation:

In scientific notation, the number of integers in the first part will always be the amount of significant figures.

For example,

1) 1.542505 x 10^17 =7 significant figures

1) 1.54 x 10^17 =3 significant figures

8 0
3 years ago
In Atomic Absorption Spectrophotometry, narrow atomic lines are desirable. However, line broadening arises from: (a) Jablonski e
LenKa [72]

Answer: b) Doppler Effect

Explanation:

Line broadening in AAS, arises due to some effects, which can occur due to a number of factors. The line width broadening effects include: Doppler, Lorentz, Self absorption, and quenching effects.

Doppler effect arises because along the line of observation, atoms will have different components of velocity.

7 0
3 years ago
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