It should be 0.25kg because you converter from g to kg and since 1g<1kg so you move the decimal to the left
The answer is D, because the collision's between molecules are elastic, not inelastic.
To develop this problem it is necessary to apply the concepts related to the Dopler effect.
The equation is defined by

Where
= Approaching velocities
= Receding velocities
c = Speed of sound
v = Emitter speed
And

Therefore using the values given we can find the velocity through,


Assuming the ratio above, we can use any f_h and f_i with the ratio 2.4 to 1


Therefore the cars goes to 145.3m/s