Answer:
![-r_{A}=k\times[BF_3]^{1}\times[NH_3]^{1}](https://tex.z-dn.net/?f=-r_%7BA%7D%3Dk%5Ctimes%5BBF_3%5D%5E%7B1%7D%5Ctimes%5BNH_3%5D%5E%7B1%7D)
Explanation:
The rate law of a chemical reaction is given by
![-r_{A}=k\times[BF_3]^{\alpha}\times[NH_3]^{\beta}](https://tex.z-dn.net/?f=-r_%7BA%7D%3Dk%5Ctimes%5BBF_3%5D%5E%7B%5Calpha%7D%5Ctimes%5BNH_3%5D%5E%7B%5Cbeta%7D)
This law can be written for any experiment, and making the quotient between those expressions the reaction orders can be found
Between experiments 1 and 2
![\frac{-r_{A1}}{{-r}_{A2}}=\left(\frac{\left[NH_3\right]_1}{\left[NH_3\right]_2}\right)^\beta](https://tex.z-dn.net/?f=%5Cfrac%7B-r_%7BA1%7D%7D%7B%7B-r%7D_%7BA2%7D%7D%3D%5Cleft%28%5Cfrac%7B%5Cleft%5BNH_3%5Cright%5D_1%7D%7B%5Cleft%5BNH_3%5Cright%5D_2%7D%5Cright%29%5E%5Cbeta)
Then the expression for the calculation of 
![\beta=\frac{ln\frac{-r_{A1}}{-r_{A2}}}{ln\left(\frac{\left[NH_3\right]_1}{\left[NH_3\right]_2}\right)}=\frac{ln\frac{0.2130}{0.1065}}{ln\left(\frac{0.250}{0.125}\right)}](https://tex.z-dn.net/?f=%5Cbeta%3D%5Cfrac%7Bln%5Cfrac%7B-r_%7BA1%7D%7D%7B-r_%7BA2%7D%7D%7D%7Bln%5Cleft%28%5Cfrac%7B%5Cleft%5BNH_3%5Cright%5D_1%7D%7B%5Cleft%5BNH_3%5Cright%5D_2%7D%5Cright%29%7D%3D%5Cfrac%7Bln%5Cfrac%7B0.2130%7D%7B0.1065%7D%7D%7Bln%5Cleft%28%5Cfrac%7B0.250%7D%7B0.125%7D%5Cright%29%7D)
Resolving
Doing the same between experiments 3 and 4 the expression for 
is
![\alpha=\frac{ln\frac{-r_{A3}}{-r_{A4}}}{ln\left(\frac{\left[BF_3\right]_3}{\left[BF_3\right]_4}\right)}=\frac{ln\frac{0.0682}{0.1193}}{ln\left(\frac{0.200}{0.350}\right)}](https://tex.z-dn.net/?f=%5Calpha%3D%5Cfrac%7Bln%5Cfrac%7B-r_%7BA3%7D%7D%7B-r_%7BA4%7D%7D%7D%7Bln%5Cleft%28%5Cfrac%7B%5Cleft%5BBF_3%5Cright%5D_3%7D%7B%5Cleft%5BBF_3%5Cright%5D_4%7D%5Cright%29%7D%3D%5Cfrac%7Bln%5Cfrac%7B0.0682%7D%7B0.1193%7D%7D%7Bln%5Cleft%28%5Cfrac%7B0.200%7D%7B0.350%7D%5Cright%29%7D)
Resolving
This means that the rate law for this reaction is
6.02x10^23; This represents the number of molecules in 1 mole of a substance.
Answer:
ΔG = 18KJ/mol
Explanation:
Given data:
ΔS = 0.09 Kj/mol.K
ΔH = 27 KJ/mol
Temperature = 100 K
ΔG = ?
Solution:
Formula:
ΔG = ΔH - TΔS
ΔH = enthalpy
ΔS = entropy
by putting values,
ΔG = 27 KJ/mol - 100K(0.09 Kj/mol.K)
ΔG = 27 KJ/mol - 9 KJ/mol
ΔG = 18KJ/mol
Answer:
No, I can not identify the contents of each bottle using solubility and polarity (with H2O) information
Explanation:
While it is true that polar substances dissolve in water and nonpolar substances do not dissolve in water, the task here is to specifically identify the contents of each of the bottles.
Solubility in water can not tell us exactly what liquid is which substance. For instance, trans-1,2-dichloroethylene, cis-1,2-dichloroethylene and cyclooctane are all insoluble in water. The fact that they do not dissolve in water does not tell us which liquid is which compound.
Even though acetic acid is miscible with water, it is not a conclusive prove that the liquid is acetic acid since other polar organic compounds are also miscible in water.
It is only by determining the boiling point of each substance that I can conclusively identify the contents of each bottle since boiling point is an intrinsic property of substances.
