Answer:
a)CN=12
b)APF=74 %
c)a=0.35 nm
d)ρ=9090.9 
Explanation:
Given that
Nickel have FCC structure
We know that in FCC structure ,in FCC 8 atoms at corner with 1/8 th part in one unit cell and 6 atoms at faces with 1/2 part in one unit cell .
Z=8 x 1/8 + 1/2 x 6 =4
Z=4
Coordination number (CN)
The number of atoms which touch the second atoms is known as coordination number.In other word the number of nearest atoms.
CN=12
Coordination number of FCC structure is 12.These 12 atoms are 4 atoms at the at corner ,4 atoms at 4 faces and 4 atoms of next unit cell.
APF

We know that for FCC

Now by putting the values

APF=0.74
APF=74 %


a=0.35 nm
Density

We know that M for Ni
M=58.69 g/mol
a=0.35 nm


ρ=9090.9 
In an endothermic reaction products are <u>HIGHER </u>than reactants in potential energy and <u>LESS </u>stable.
Explanation:
Energy is input into the reaction in an endothermic reaction. This means the products are of a higher energy level than the reactants. Therefore the reaction increases Gibb's free energy and reduces entropy. Remember in thermodynamic stability involves an increase in entropy and a decrease in Gibbs free energy. Therefore the products are less stable than the reactants. This is why endothermic reactions do not occur spontaneously like exothermic reactions.
Answer:
A. One unpaired electron
B. 5 unpaired electrons
Explanation:
In A ,Fe is in +3 oxidation state and Electronic configuration- [Ar]3d5
And NO2 is a strong field ligand hence it causes pairing in t2g orbitals and results one unpaired electron in dZX orbital.
In B, also Fe is in +3 oxidation state but F is weak field ligand hence causes no pairing of Electrons hence it results 5 unpaired electrons with electronic configuration t2g^3 eg^2