Consider the halogenation of ethene is as follows:
CH₂=CH₂(g) + X₂(g) → H₂CX-CH₂X(g)
We can expect that this reaction occurring by breaking of a C=C bond and forming of two C-X bonds.
When bond break it is endothermic and when bond is formed it is exothermic.
So we can calculate the overall enthalpy change as a sum of the required bonds in the products:
Part a)
C=C break = +611 kJ
2 C-F formed = (2 * - 552) = -1104 kJ
Δ H = + 611 - 1104 = - 493 kJ
2C-Cl formed = (2 * -339) = - 678 kJ
ΔH = + 611 - 678 = -67 kJ
2 C-Br formed = (2 * -280) = -560 kJ
ΔH = + 611 - 560 = + 51 kJ
2 C-I Formed = (2 * -209) = -418 kJ
ΔH = + 611 - 418 = + 193 kJ
Part b)
As we can see that the highest exothermic bond formed is C-F bond so from bond energies we can found that addition of fluoride is the most exothermic reaction
The average atomic mass of Sn is 118.71 g/mol
the percentage of heaviest Sn is 5.80%
the given mass of Sn is 82g
The total moles of Sn will be = mass / atomic mass = 82/118.71=0.691
Total atoms of Sn in 82g = 
the percentage of heaviest Sn is 5.80%
So the total atoms of
= 5.80% X 
Total atoms of
=
atoms
the mass of
will be = 
Are produced along with a large quantitu of heat
Using the same anchor points, he determined the freezing temperature for water to be 0 degree and the boiling temperature 100 degrees. The Celsius scale is known as a Universal System Unit. It is used throughout science and in most countries.