Answer:
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NaOH reacts with CH3COOH in 1:1 molar ratio to produce CH3COONa
NaOH + CH3COOH → CH3COONa + H2O
Mol CH3COOH in 52.0mL of 0.35M solution = 52.0/1000*0.35 = 0.0182 mol CH3COOH
Mol NaOH in 19.0mL of 0.40M solution = 19.0/1000*0.40 = 0.0076 mol NaOH
These will react to produce 0.0076 mol CH3COONa and there will be 0.0182 - 0.0076 = 0.0106 mol CH3COOH remaining in solution unreacted . Total volume of solution = 52.0+19.0 = 71mL or 0.071L
Molarity of CH3COOH = 0.0106/0.071 = 0.1493M
CH3COONa = 0.0076 / 0.071 = 0.1070M
pKa acetic acid = - log Ka = -log 1.8*10^-5 = 4.74.
pH using Henderson - Hasselbalch equation:
pH = pKa + log ([salt]/[acid])
pH = 4.74 + log ( 0.1070/0.1493)
pH = 4.74 + log 0.717
pH = 4.74 + (-0.14)
pH = 4.60.
Answer:
pH = 8.34
Explanation:
The equilbriums of the amphoteric HCO₃⁻ (Ion of NaHCO₃) are:
H₂CO₃ ⇄ <em>HCO₃⁻</em> + H⁺ Ka1 <em>-Here, HCO₃⁻ is acting as a base-</em>
<em>HCO₃⁻</em>⇄ CO₃²⁻ + H⁺ Ka2 <em>-Here, is acting as an acid-</em>
Where Ka1 = 4.3x10⁻⁷ and Ka2 = 4.8x10⁻¹¹. As pKa = -log Ka:
pKa1 = 6.37; pKa2 = 10.32
As the pH of amphoteric salts is:
pH = (pKa1 + pKa2) / 2
<h2>pH = 8.34</h2>
The size of atom reduces
Electronic configuration of sodium -
2,8,1
In order to become stable it loses one electron and becomes positive ion.
It's size reduces.
