Answer:
and 
Explanation:
The equation for the reaction is AgNO3(aq) + KCl(aq) ==> AgCl(s) + KNO3(aq)
With all the ions, it is
(aq) + 
(aq) + (aq) + 
(aq) ==> AgCl(s) +
and do not change, so they are the spectator ions and are removed
The ionic equation is:
(aq) + (aq) ==> AgCl(s)
We do a heat balance to solve this:
(m cp ΔT)water = -(m cp ΔT)metal
100.8 (4.18) (27 - 22) = -65 (cp)(27-100)
cp = 100.8 (4.18) (27 - 22) / (-65 (27-100))
cp = 0.44 J/ (°C × g)
The specific heat of the metal is 0.44 J/ (°C × g)
Unfortunately, you failed to include the table 1 from which the molar heat capacity of aluminum could have been obtained. However, as a general rule, the heat needed to raise the temperature of a certain substance by certain degrees is calculated through the equation,
H = mcpdT
where H is heat, m is mass, cp is specific heat capacity, and dT is change in temperature. From a reliable source, cp for aluminum is equal to 0.215 cal/g°C. Substituting this to the equation,
H = (260.5 g)(0.215 cal/g°C)(125°C - 0)
H = 7000.94 cal
