Na2C03 is formed through the reaction of
NaOH and H2CO3 namely sodium hydroxide and carbonic acid
NaOH -> strong base
H2CO3-> weak acid
Positive ions are formed by atoms or molecules suffering an inelastic collision with an energetic electron in which an electron is lost from the atom or molecule (electron impact ionization). The degree of ionization of the plasma depends strongly on the electron density and energy distribution in the gas.
I believe it would be Boyle's Law
(P [is proportional to] 1/V)
P being pressure
V being volume