The correct answers are :
Changing the volume of the system.
Changing the temperature of the system.
Equilibrium will remain unaffected if the concentration of products and reactants are kept the same, and the temperature of the system is kept constant.
As the system is closed, we cannot add or remove products or reactants.
Change in temperature will shift the chemical equilibrium towards the reactant or product depending on whether the reaction is exothermic or endothermic.
Also change in volume will shift the chemical equilibrium of a chemical reaction if the reactants or products or both are gases.
Given :
Molarity of sulfuric acid solution is 3.0 M.
Amount of sulfuric acid present in solution is 9.809 g.
To Find :
The volume of solution.
Solution :
We know, molarity is given by :
Therefore, volume required is 33.33 ml .
Step one calculate the moles of each element
that is moles= % composition/molar mass
molar mass of Ca = 40g/mol, S= 32 g/mol , O= 16 g/mol
moles of Ca = 29.4 /40g/mol=0.735 moles, S= 23.5/32 =0.734 moles, O= 47.1/16= 2.94 moles
calculate the mole ratio by dividing each mole with smallest mole that is 0.734
Ca= 0.735/0.734= 1, S= 0.734/0.734 =1, O = 2.94/ 0.734= 4
therefore the emipical formula = CaSO4
STP is the abbreviation of standard condition for temperature and pressure which is 273.15K temperature and 1.013× 10^5 Pa pressure. Since the pressure and temperature changes, I assume the question would ask about the result of the volume. The temperature used in ideal gas should be Kelvin, so 27 Celcius would be 300.15K.
The calculation would be
PV=T
V=T/P
V2/V1= T2*P1/T1*P2
V2/V1=273.15K* 90^10^3Pa/ 300.15K * 1.013× 10^5 Pa
V2= 0.81904 * 51.7ml
V2= 42.34ml
