Answer:
The rate at which ammonia is being produced is 0.41 kg/sec.
Explanation:
Haber reaction
Volume of dinitrogen consumed in a second = 505 L
Temperature at which reaction is carried out,T= 172°C = 445.15 K
Pressure at which reaction is carried out, P = 0.88 atm
Let the moles of dinitrogen be n.
Using an Ideal gas equation:


According to reaction , 1 mol of ditnitrogen gas produces 2 moles of ammonia.
Then 12.1597 mol of dinitrogen will produce :
of ammonia
Mass of 24.3194 moles of ammonia =24.3194 mol × 17 g/mol
=413.43 g=0.41343 kg ≈ 0.41 kg
505 L of dinitrogen are consumed in 1 second to produce 0.41 kg of ammonia in 1 second. So the rate at which ammonia is being produced is 0.41 kg/sec.
Answer:
V ∝ abc
Explanation:
This task is a joint variation task involving only direct proportionality:
Direct variation is one in which two variables are in direct proportionality to each other. This means that as one increases, the other variable also increases and vice - versa.
Joint variation is one in which one variable is dependent on two or more variables and varies directly as each of them.
In this exercise:
If a ∝ b and a ∝ c, then a ∝ bc
Taking the above three proportionalities,
V ∝ a ∝ b ∝ c
V ∝ a ∝ bc
V ∝ abc
Answer:
yes
Explanation:
Solubility is an observation and no chemical reaction takes place. The composition of the compound/element is not changed.
- Hope that helped! Please let me know if you need further explanation.
Answer:
Rubidium is used in vacuum tubes as a getter, a material that combines with and removes trace gases from vacuum tubes. It is also used in the manufacture of photocells and in special glasses. Since it is easily ionized, it might be used as a propellant in ion engines on spacecraft.
Symbol: Rb (37)
Atomic Weight: 85.4678
Atomic Number: 37
Number of Stable Isotopes: 1 (View all isotope .
Answer:
a. 1.7 × 10⁻⁴ mol·L⁻¹; b. 5.5 × 10⁻⁹ mol·L⁻¹
c. 2.3 × 10⁻⁴ mol·L⁻¹; 5.5 × 10⁻⁸ mol·L⁻¹
Explanation:
a. Silver iodate
Let s = the molar solubility.
AgIO₃(s) ⇌ Ag⁺(aq) + IO₃⁻(aq); Ksp = 3.0 × 10⁻⁸
E/mol·L⁻¹: s s
![K_{sp} =\text{[Ag$^{+}$][IO$_{3}$$^{-}$]} = s\times s = s^{2} = 3.0\times 10^{-8}\\s = \sqrt{3.0\times 10^{-8}} \text{ mol/L} = 1.7 \times 10^{-4} \text{ mol/L}](https://tex.z-dn.net/?f=K_%7Bsp%7D%20%3D%5Ctext%7B%5BAg%24%5E%7B%2B%7D%24%5D%5BIO%24_%7B3%7D%24%24%5E%7B-%7D%24%5D%7D%20%3D%20s%5Ctimes%20s%20%3D%20%20s%5E%7B2%7D%20%3D%203.0%5Ctimes%2010%5E%7B-8%7D%5C%5Cs%20%3D%20%5Csqrt%7B3.0%5Ctimes%2010%5E%7B-8%7D%7D%20%5Ctext%7B%20mol%2FL%7D%20%3D%201.7%20%5Ctimes%2010%5E%7B-4%7D%20%5Ctext%7B%20mol%2FL%7D)
b. Barium sulfate
BaSO₄(s) ⇌ Ba²⁺(aq) + SO₄²⁻(aq); Ksp = 1.1 × 10⁻¹⁰
I/mol·L⁻¹: 0.02 0
C/mol·L⁻¹: +s +s
E/mol·L⁻¹: 0.02 + s s
![K_{sp} =\text{[Ba$^{2+}$][SO$_{4}$$^{2-}$]} = (0.02 + s) \times s \approx 0.02s = 1.1\times 10^{-10}\\s = \dfrac{1.1\times 10^{-10}}{0.02} \text{ mol/L} = 5.5 \times 10^{-9} \text{ mol/L}](https://tex.z-dn.net/?f=K_%7Bsp%7D%20%3D%5Ctext%7B%5BBa%24%5E%7B2%2B%7D%24%5D%5BSO%24_%7B4%7D%24%24%5E%7B2-%7D%24%5D%7D%20%3D%20%280.02%20%2B%20s%29%20%5Ctimes%20s%20%5Capprox%20%200.02s%20%3D%201.1%5Ctimes%2010%5E%7B-10%7D%5C%5Cs%20%3D%20%5Cdfrac%7B1.1%5Ctimes%2010%5E%7B-10%7D%7D%7B0.02%7D%20%5Ctext%7B%20mol%2FL%7D%20%3D%205.5%20%5Ctimes%2010%5E%7B-9%7D%20%5Ctext%7B%20mol%2FL%7D)
c. Using ionic strength and activities
(i) Calculate the ionic strength of 0.02 mol·L⁻¹ Ba(NO₃)₂
The formula for ionic strength is
![\mu = \dfrac{1}{2} \sum_{i} {c_{i}z_{i}^{2}}\\\\\mu = \dfrac{1}{2} (\text{[Ba$^{2+}$]}\cdot (2+)^{2} + \text{[NO$_{3}$$^{-}$]}\times(-1)^{2}) = \dfrac{1}{2} (\text{0.02}\times 4 + \text{0.04}\times1)= \dfrac{1}{2} (0.08 + 0.04)\\\\= \dfrac{1}{2} \times0.12 = 0.06](https://tex.z-dn.net/?f=%5Cmu%20%3D%20%5Cdfrac%7B1%7D%7B2%7D%20%5Csum_%7Bi%7D%20%7Bc_%7Bi%7Dz_%7Bi%7D%5E%7B2%7D%7D%5C%5C%5C%5C%5Cmu%20%3D%20%5Cdfrac%7B1%7D%7B2%7D%20%28%5Ctext%7B%5BBa%24%5E%7B2%2B%7D%24%5D%7D%5Ccdot%20%282%2B%29%5E%7B2%7D%20%2B%20%5Ctext%7B%5BNO%24_%7B3%7D%24%24%5E%7B-%7D%24%5D%7D%5Ctimes%28-1%29%5E%7B2%7D%29%20%3D%20%5Cdfrac%7B1%7D%7B2%7D%20%28%5Ctext%7B0.02%7D%5Ctimes%204%20%2B%20%5Ctext%7B0.04%7D%5Ctimes1%29%3D%20%5Cdfrac%7B1%7D%7B2%7D%20%280.08%20%2B%200.04%29%5C%5C%5C%5C%3D%20%5Cdfrac%7B1%7D%7B2%7D%20%5Ctimes0.12%20%3D%200.06)
(ii) Silver iodate
a. Calculate the activity coefficients of the ions

b. Calculate the solubility
AgIO₃(s) ⇌ Ag⁺(aq) + IO₃⁻(aq)
![K_{sp} =\text{[Ag$^{+}$]$\gamma_{Ag^{+}}$[IO$_{3}$$^{-}$]$\gamma_{IO_{3}^{-}}$} = s\times0.75\times s \times 0.75 =0.56s^{2}= 3.0 \times 10^{-8}\\s^{2} = \dfrac{3.0 \times 10^{-8}}{0.56} = 5.3 \times 10^{-8}\\\\s =2.3 \times 10^{-4}\text{ mol/L}](https://tex.z-dn.net/?f=K_%7Bsp%7D%20%3D%5Ctext%7B%5BAg%24%5E%7B%2B%7D%24%5D%24%5Cgamma_%7BAg%5E%7B%2B%7D%7D%24%5BIO%24_%7B3%7D%24%24%5E%7B-%7D%24%5D%24%5Cgamma_%7BIO_%7B3%7D%5E%7B-%7D%7D%24%7D%20%3D%20s%5Ctimes0.75%5Ctimes%20s%20%5Ctimes%200.75%20%3D0.56s%5E%7B2%7D%3D%203.0%20%5Ctimes%2010%5E%7B-8%7D%5C%5Cs%5E%7B2%7D%20%3D%20%5Cdfrac%7B3.0%20%5Ctimes%2010%5E%7B-8%7D%7D%7B0.56%7D%20%3D%205.3%20%5Ctimes%2010%5E%7B-8%7D%5C%5C%5C%5Cs%20%3D2.3%20%5Ctimes%2010%5E%7B-4%7D%5Ctext%7B%20mol%2FL%7D)
(iii) Barium sulfate
a. Calculate the activity coefficients of the ions

b. Calculate the solubility
BaSO₄(s) ⇌ Ba²⁺(aq) + SO₄²⁻(aq
![K_{sp} =\text{[Ba$^{2+}$]$\gamma_{ Ba^{2+}}$[SO$_{4}$$^{2-}$]$\gamma_{ SO_{4}^{2-}}$} = (0.02 + s) \times 0.32\times s\times 0.32 \approx 0.02\times0.10s\\2.0\times 10^{-3}s = 1.1 \times 10^{-10}\\s = \dfrac{1.1\times 10^{-10}}{2.0 \times 10^{-3}} \text{ mol/L} = 5.5 \times 10^{-8} \text{ mol/L}](https://tex.z-dn.net/?f=K_%7Bsp%7D%20%3D%5Ctext%7B%5BBa%24%5E%7B2%2B%7D%24%5D%24%5Cgamma_%7B%20Ba%5E%7B2%2B%7D%7D%24%5BSO%24_%7B4%7D%24%24%5E%7B2-%7D%24%5D%24%5Cgamma_%7B%20SO_%7B4%7D%5E%7B2-%7D%7D%24%7D%20%3D%20%280.02%20%2B%20s%29%20%5Ctimes%200.32%5Ctimes%20s%5Ctimes%200.32%20%5Capprox%20%200.02%5Ctimes0.10s%5C%5C2.0%5Ctimes%2010%5E%7B-3%7Ds%20%3D%201.1%20%5Ctimes%2010%5E%7B-10%7D%5C%5Cs%20%3D%20%5Cdfrac%7B1.1%5Ctimes%2010%5E%7B-10%7D%7D%7B2.0%20%5Ctimes%2010%5E%7B-3%7D%7D%20%5Ctext%7B%20mol%2FL%7D%20%3D%205.5%20%5Ctimes%2010%5E%7B-8%7D%20%5Ctext%7B%20mol%2FL%7D)