(a) One form of the Clausius-Clapeyron equation is
ln(P₂/P₁) = (ΔHv/R) * (1/T₁ - 1/T₂); where in this case:
Solving for ΔHv:
- ΔHv = R * ln(P₂/P₁) / (1/T₁ - 1/T₂)
- ΔHv = 8.31 J/molK * ln(5.3/1.3) / (1/358.96 - 1/392.46)
(b) <em>Normal boiling point means</em> that P = 1 atm = 101.325 kPa. We use the same formula, using the same values for P₁ and T₁, and replacing P₂ with atmosferic pressure, <u>solving for T₂</u>:
- ln(P₂/P₁) = (ΔHv/R) * (1/T₁ - 1/T₂)
- 1/T₂ = 1/T₁ - [ ln(P₂/P₁) / (ΔHv/R) ]
- 1/T₂ = 1/358.96 K - [ ln(101.325/1.3) / (49111.12/8.31) ]
(c)<em> The enthalpy of vaporization</em> was calculated in part (a), and it does not vary depending on temperature, meaning <u>that at the boiling point the enthalpy of vaporization ΔHv is still 49111.12 J/molK</u>.
95.6 cal
are needed.
Explanation:
Use the following equation:
q
=
m
c
Δ
T
,
where:
q
is heat energy,
m
is mass,
c
is specific heat capacity, and
Δ
T
is the change in temperature.
Δ
T
=
T
final
−
T
initial
Known
m
=
125 g
c
Pb
=
0.130
J
g
⋅
∘
C
T
initial
=
17.5
∘
C
T
final
=
42.1
∘
C
Δ
T
=
42.1
∘
C
−
17.5
∘
C
=
24.6
∘
C
Unknown
q
Solution
Plug the known values into the equation and solve.
q
=
(
125
g
)
×
(
0.130
J
g
⋅
∘
C
)
×
(
24.6
∘
C
)
=
400. J
(rounded to three significant figures)
Convert Joules to calories
1 J
=
0.2389 cal
to four significant figures.
400
.
J
×
0.2389
cal
1
J
=
95.6 cal
(rounded to three significant figures)
95.6 cal
are needed.
Answer:
15
Explanation:
Because the ratio of copper in the solution is 15
Answer:
1-10 μL
Explanation:
Gas Chromatography (GC) is a method of separating the constituents of a complex mixture by taking advantage of their different rates of movement in a solvent over an adsorbent medium. Gas Chromatography (GC) is a means of separation and analysis that utilises fractional separation. It is based on the principle that if a fluid containing a number of substances is allowed to pass through an adsorbent medium , the different substances in the fluid may travel at different rates and be separated.
The approximate volume injected through an inlet by using a split injection into a Gas Chromatography (GC) contains a sample with an approximate value of analyte which varies from 1-10 μL.
In order to adjust for injection volume inaccuracy, the technique used is known as Internal Standard.
Answer:
Ca(ClO3)2
Explanation:
The chemical formula of calcium chlorate is Ca(ClO3)2, which means in this molecule, Ca2+ ion is bonded to two ClO3- ions. So the formula can be expended to O3Cl-Ca-ClO3, or CaCl2O6 (basically times the numbers of the elements inside the bracket by the number outside the bracket.
