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velikii [3]
3 years ago
13

Each of the following substrates can react with a nucleophile in a substitution reaction. Select the substrate that cannot under

go substitution via neighboring group participation (NGP). A B C D

Chemistry
1 answer:
leva [86]3 years ago
5 0

Answer:

Substrate D

Explanation:

In substitution reactions the tertiary substrates cannot undergo substitution via neighboring group participation (NGP) due to the steric impediment, this means that the volume occupied by the substituents is very large and makes it impossible to attack the nucleophile to the substrate carbon.

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The size v=masse/density
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4 0
3 years ago
The rate constant for the decomposition of nitrogen dioxide NO2(g) LaTeX: \longrightarrow⟶ NO (g) + 1/2 O2(g) with a laser beam
aleksley [76]

Answer :

The time taken by the reaction is 19.2 seconds.

The order of reaction is, second order reaction.

Explanation :

The general formula to determine the unit of rate constant is:

(Concentration)^{(1-n)}(Time)^{-1}

Unit of rate constant                           Order of reaction

Concentration/Time                                        0

Time^{-1}                                                              1

(Concentration)^{-1}Time^{-1}                                 2

As the unit of rate constant is M^{-1}min^{-1}. So, the order of reaction is second order.

The expression used for second order kinetics is:

kt=\frac{1}{[A_t]}-\frac{1}{[A_o]}

where,

k = rate constant = 1.95M^{-1}s^{-1}

t = time = ?

[A_t] = final concentration = 0.97 M

[A_o] = initial concentration = 2.48 M

Now put all the given values in the above expression, we get:

1.95\times t=\frac{1}{0.97}-\frac{1}{2.48}

t=0.32min=0.32\times 60s=19.2s

Therefore, the time taken by the reaction is 19.2 seconds.

8 0
3 years ago
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8 0
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natka813 [3]
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You need to use stochio

8 0
3 years ago
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Elena L [17]

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6 0
3 years ago
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