Answer:
see note under explanation
Explanation:
When describing system and surroundings the system is typically defined as the 'object of interest' being studied and surroundings 'everything else'. In thermodynamics heat flow is typically defined as endothermic or exothermic. However, one should realize that the terms endothermic and exothermic are in reference to the 'system' or object of interest being studied. For example if heat is transferred from a warm object to a cooler object it is imperative that the system be defined 1st. So, with that, assume the system is a warm metal cylinder being added into cooler water. When describing heat flow then the process is exothermic with respect to the metal cylinder (the system) but endothermic to the water and surroundings (everything else).
Answer:
159 mg caffeine is being extracted in 60 mL dichloromethane
Explanation:
Given that:
mass of caffeine in 100 mL of water = 600 mg
Volume of the water = 100 mL
Partition co-efficient (K) = 4.6
mass of caffeine extracted = ??? (unknown)
The portion of the DCM = 60 mL
Partial co-efficient (K) = 
where; 
solubility of compound in the organic solvent and 
= solubility in aqueous water.
So; we can represent our data as:
÷ 
Since one part of the portion is A and the other part is B
A+B = 60 mL
A+B = 0.60
A= 0.60 - B
4.6=
÷ 
4.6 = 
4.6 × =
4.6 B 
= 0.6 - B
2.76 B = 0.6 - B
2.76 + B = 0.6
3.76 B = 0.6
B = 
B = 0.159 g
B = 159 mg
∴ 159 mg caffeine is being extracted from the 100 mL of water containing 600 mg of caffeine with one portion of in 60 mL dichloromethane.
Answer:
0.4 moles
Explanation:
To convert between moles and grams you need the molar mass of the compound. The molar mass of of CaCO3 is 100.09g/mol. You use that as the unit converter.
40gCaCO3* 1mol CaCO3/100.09gCaCO3 = 0.399640 mol CaCO3
This rounds to 0.4 moles CaCO3
Using electronegativity difference is a good guide to the ionic/ covalent nature. Large differences indicate greater ionic character, small differences more covalent character. The larger the difference in electronegativity the more ionic properties a bond is said to have. The smaller the difference in electronegativity the more covalent properties a bond is said to have.
Ionic bonding is formed through electrostatic attraction between a cation and anion. Foe example, Sodium fluoride has ionic bonding because it is composed by sodium and Fluorine (a non metal). On the other hand, covalent bonding is characterized by atoms sharing pairs of electrons. For example; methane has covalent bonding; carbon has 4 valence electrons and hydrogen has 1; when they bond they have a total of 8 electrons and satisfies the octet rule.
The Beer-Lambert law states that A = E*c*l where A is absorbance, E is the molar absorbance coeffecient, c is concentration and l is path length. Therefore the absorbance is directly proportional to concentration, and by increasing the concentration by a factor of 3, absorbance will increase by a factor of 3 giving A = 1.584
