1answer.
Ask question
Login Signup
Ask question
All categories
  • English
  • Mathematics
  • Social Studies
  • Business
  • History
  • Health
  • Geography
  • Biology
  • Physics
  • Chemistry
  • Computers and Technology
  • Arts
  • World Languages
  • Spanish
  • French
  • German
  • Advanced Placement (AP)
  • SAT
  • Medicine
  • Law
  • Engineering
Paul [167]
3 years ago
12

The value of Ka for nitrous acid (HNO2) at 25 ∘C is 4.5×10−4 .a. Write the chemical equation for the equilibrium that correspond

s to Ka1. H+(aq)+NO−2(aq)⇌HNO2(aq)2. HNO2(aq)⇌H+(aq)+NO−2(aq)3. HNO2(aq)⇌H−(aq)+NO+2(aq)4. HNO2(aq)+H+(aq)⇌H2NO+2(aq)5. HNO2(aq)+H−(aq)⇌H2NO+2(aq)​b. By using the value of Ka , calculate ΔG∘ for the dissociation of nitrous acid in aqueous solution. c. What is the value of ΔG at equilibrium? d. What is the value of ΔG when [H+] = 5.9×10−2 M , [NO−2] = 6.7×10−4 M , and [HNO2] = 0.21 M ?
Chemistry
1 answer:
kvv77 [185]3 years ago
6 0

Answers and Explanation:

a)- The chemical equation for the corresponden equilibrium of Ka1 is:

2. HNO2(aq)⇌H+(aq)+NO−2

Because Ka1 correspond to a dissociation equilibrium. Nitrous acid (HNO₂) losses a proton (H⁺) and gives the monovalent anion NO₂⁻.

b)- The relation between Ka and the free energy change (ΔG) is given by the following equation:

ΔG= ΔGº + RT ln Q

Where T is the temperature (T= 25ºc= 298 K) and R is the gases constant (8.314 J/K.mol)

At the equilibrium: ΔG=0 and Q= Ka. So, we can calculate ΔGº by introducing the value of Ka:

⇒ 0 = ΔGº + RT ln Ka

   ΔGº= - RT ln Ka

   ΔGº= -8.314 J/K.mol x 298 K x ln (4.5 10⁻⁴)

  ΔGº= 19092.8 J/mol

c)- According to the previous demonstation, at equilibrium ΔG= 0.

d)- In a non-equilibrium condition, we have Q which is calculated with the concentrations of products and reactions in a non equilibrium state:

ΔG= ΔGº + RT ln Q

Q= ((H⁺) (NO₂⁻))/(HNO₂)

Q= ( (5.9 10⁻² M) x (6.7 10⁻⁴ M) ) / (0.21 M)

Q= 1.88 10⁻⁴

We know that   ΔGº= 19092.8 J/mol, so:

ΔG= ΔGº + RT ln Q

ΔG= 19092.8 J/mol + (8.314 J/K.mol x 298 K x ln (1.88 10⁻⁴)

ΔG= -2162.4 J/mol

Notice that ΔG<0, so the process is spontaneous in that direction.

You might be interested in
What should a simplified model of a large molecule like glucose show?
maxonik [38]

Glucose is the simplest sugar and carbohydrate that provides energy. The simplified model of glucose (C₆H₁₂O₆) shows carbon, hydrogen, and oxygen atoms linked together.

<h3>What is glucose?</h3>

Glucose is an example of a carbohydrate macromolecule that is further classified as a monosaccharide. They are crystalline and fundamental units of carbohydrates.

The molecular formula of glucose is C₆H₁₂O₆ and the mass is 180.156 g/mol. It is an aldohexose that contains an aldehydic functional group. In its structure, there are six oxygen atoms, six carbon atoms, and twelve hydrogen atoms.

Therefore, the glucose molecule is composed of C, H, and O.

Learn more about glucose here:

brainly.com/question/2396657

#SPJ1

5 0
1 year ago
Identify the type of reaction occurring based on the description
postnew [5]

Answer:double displacement

Explanation:I just did it

8 0
3 years ago
Molar mass of A1C1 3
Kamila [148]

Answer:

Gold(III) chloride

5 0
3 years ago
A sample of gaseous methyl ether has a mass of 8.12g and occupies a volume of 3.96L at STP. What is the molecular weight of meth
Naya [18.7K]
Molar volume is when 1 mol of any gas occupies 22.4 L at STP.
Methyl ether has a mass of 8.12 g,
Volume occupied - 3.96 L
If 22.4 L occupied by 1 mol of gas
Then 3.96 L occupied by 1/22.4 x 3.96 = 0.176 mol of gas
The mass of 0.176 mol = 8.12 g
Molar mass is mass of 1 mol
Therefore mass of 1 mol = 8.12/0.176 = 46.1
Molecular weight is 46.1 g/mol
5 0
3 years ago
A 25.00 ml sample of h3po4 solution is neutralized by exactly 54.93 ml of 0.04345 m ca(oh)2. what is the molarity of the h3po4 s
son4ous [18]
The neutralization equation is:
3 Ca(OH)₂ + 2 H₃PO₄ → Ca₃(PO₄)₂ + 6 H₂O

From this equation we can see that 3 moles of Ca(OH)₂ react with 2 moles of H₃PO₄

Numbers of mmol of Ca(OH)₂ = M x V = 0.04345 x 54.93 = 2.387 mmol

Number of mmol of H₃PO₄ = 2.387 x (2/3) = 1.591 mmol

Molarity of solution = n (mmol) / V(ml) = 1.591 / 25 = 0.0636 M
8 0
3 years ago
Read 2 more answers
Other questions:
  • How many moles are in 8.30x10^23 molecules of H2o
    7·2 answers
  • If you burn 42.5 g of hydrogen and produce 3.80 × 102 g of water, how much oxygen reacted?
    9·1 answer
  • Chemical reactions forming ions _____.
    7·1 answer
  • An aluminum ion has a charge of +3, and an oxide has a charge of -2. What would be the product of a reaction between these two e
    9·1 answer
  • Which of these is a chemical property of a substance?
    15·1 answer
  • Will give brainliest this is simple plz help
    10·1 answer
  • Which exponential expression represents the numerical expression 112⋅112⋅112⋅112? ​(112)4​
    14·2 answers
  • The longest day, and shortest night, of the year occurs on the
    15·1 answer
  • How many molecules are in 4.5 moles of Ca(OH),?​
    14·2 answers
  • It is defined as the number of particles per mole of a substance. *
    15·1 answer
Add answer
Login
Not registered? Fast signup
Signup
Login Signup
Ask question!