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Kazeer [188]
3 years ago
7

Consider the formation of nitryl fluoride: 2NO2(g)+F2(g)⇌2NO2F(g) The reaction is first order in F2 and second order overall. Wh

at is the rate law? View Available Hint(s) Consider the formation of nitryl fluoride: The reaction is first order in and second order overall. What is the rate law? rate=k[NO2]2[F2]2 rate=k[NO2][F2]2 rate=k[F2] rate=k[NO2] rate=k[NO2][F2] rate=k[NO2]2[F2]
Chemistry
1 answer:
Dahasolnce [82]3 years ago
7 0

Answer:

Rate = k[NO_{2}][F_{2}]

Explanation:

  • Two reactants are present in this reaction which are NO_{2}and F_{2}
  • We know overall order of a reaction is summation of individual order with respect to reactants present in rate law equation.
  • Here, overall order of reaction is 2 including first order with respect to F_{2}
  • So, rate of reaction should also be first order with respect to another reactant i.e. first order with respect to NO_{2}
  • So, rate law: rate = k[NO_{2}][F_{2}]
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Which of the following does not state a property of electricity?
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Answer:

(a) [Noble gas] ns² np⁵: Number of unpaired electron is 1 and belongs to group 17 i.e. halogen group of the periodic table.

(b) [noble gas] ns² (n-1)d²: Number of unpaired electron is 2 and belongs to group 4 of the periodic table.

(c) [noble gas] ns² (n-1)d¹⁰ np¹: Number of unpaired electron is 1 and belongs to group 13 of the periodic table.

(d)[noble gas] ns² (n-2)f⁶ : Number of unpaired electron is 6 and belongs to group 8 of the periodic table.

Explanation:

In the Periodic table, the chemical elements are arranged in 7 rows, called periods and 18 columns, called groups. They are organized in increasing order of atomic numbers.

(a) [Noble gas] ns² np⁵

As the total number of electrons in the p-orbital is 5. Therefore, the number of unpaired electron is 1.

This element has 2 electrons in ns orbital and 5 electrons in np orbital. <u>So there are 7 valence electrons.</u>

Therefore, this element belongs to the group 17 i.e. halogen group of the periodic table.

(b) [noble gas] ns² (n-1)d²

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This element has 2 electrons in ns orbital and 2 electrons in (n-1)d orbital. So there are <u>4 valence electrons.</u>

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This element has 2 electrons in ns orbital and 1 electron in np orbital. So there are <u>3 valence electrons</u>.

Therefore, this element belongs to the group 13 of the periodic table.

(d)[noble gas] ns² (n-2)f⁶

As the total number of electrons in the f-orbital is 6. Therefore, the number of unpaired electron is 6.

This element has 2 electrons in ns orbital and 6 electrons in (n-2)f orbital. So there are <u>8 valence electrons.</u>

Therefore, this element belongs to the group 8 of the periodic table.

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