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Paul [167]
3 years ago
14

If a 0.710 m 0.710 m aqueous solution freezes at − 2.00 ∘ C, −2.00 ∘C, what is the van't Hoff factor, i , i, of the solute?

Chemistry
1 answer:
Lena [83]3 years ago
4 0

Answer:

The van't Hoff factor of the solute is 1.51

Explanation:

Step 1: Data given

Molality = 0.710 molal

The aqueous solution freezes at − 2.00°C

Freezing point depression constant of water = 1.86 °C/m

Step 2: Calculate the van't Hoff factor

ΔT = i*Kf * m

⇒ with ΔT = The difference between the feezing point of pure and solution = 2.00°C

⇒ i the van't Hoff factor = TO BE DETERMINED

⇒ Kf = Freezing point depression constant of water = 1.86 °C/m

⇒ m = the molality of the solution = 0.710 molal

2.00 = i * 1.86 * 0.710

i = 1.51

The van't Hoff factor of the solute is 1.51

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3 years ago
At 2°C, the vapor pressure of pure water is 23.76 mmHg and that of a certain seawater sample is 23.09 mmHg. Assuming that seawat
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Answer:

0.808  M

Explanation:

Using Raoult's Law

\frac{P_s}{Pi}= x_i

where:

P_s = vapor pressure of sea water( solution) = 23.09 mmHg

P_i = vapor pressure of pure water (solute) = 23.76 mmHg

x_i = mole fraction of water

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x_2 = 1- x_i

x_2 = 1- 0.9718

x_2 = 0.0282

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x_2 = \frac{n_2}{n_i+n_2}  ------ equation (2)

where; (n_2) = number of moles of sea water

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equating above equation 1 and 2; we have :

\frac{n_2}{n_i}= \frac{0.0282}{0.9178}

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