Answer: pH of HCl =5, HNO3 = 1,
NaOH = 9, KOH = 12
Explanation:
pH = -log [H+ ]
1. 1.0 x 10^-5 M HCl
pH = - log (1.0 x 10^-5)
= 5 - log 1 = 5
2. 0.1 M HNO3
pH = - log (1.0 x 10 ^ -1)
pH = 1 - log 1 = 1
3. 1.0 x 10^-5 NaOH
pOH = - log (1.0 x 10^-5)
pOH = 5 - log 1 = 5
pH + pOH = 14
Therefore , pH = 14 - 5 = 9
4. 0.01 M KOH
pOH = - log ( 1.0 x 10^ -2)
= 2 - log 1 = 2
pH + pOH = 14
Therefore, pH = 14 - 2 = 12
Answer:
a) 
b) entropy of the sistem equal to a), entropy of the universe grater than a).
Explanation:
a) The change of entropy for a reversible process:


The energy balance:
![\delta U=[tex]\delta Q- \delta W](https://tex.z-dn.net/?f=%5Cdelta%20U%3D%5Btex%5D%5Cdelta%20Q-%20%5Cdelta%20W)
If the process is isothermical the U doesn't change:
![0=[tex]\delta Q- \delta W](https://tex.z-dn.net/?f=0%3D%5Btex%5D%5Cdelta%20Q-%20%5Cdelta%20W)


The work:

If it is an ideal gas:


Solving:

Replacing:


Given that it's a compression: V2<V1 and ln(V2/V1)<0. So:

b) The entropy change of the sistem will be equal to the calculated in a), but the change of entropy of the universe will be 0 in a) (reversible process) and in b) has to be positive given that it is an irreversible process.
<u>Answer:</u> The concentration of solute is 0.503 mol/L
<u>Explanation:</u>
To calculate the concentration of solute, we use the equation for osmotic pressure, which is:

where,
= osmotic pressure of the solution = 24 atm
i = Van't hoff factor = 2 (for NaCl)
c = concentration of solute = ?
R = Gas constant = 
T = temperature of the solution = ![25^oC=[273+25]=298K](https://tex.z-dn.net/?f=25%5EoC%3D%5B273%2B25%5D%3D298K)
Putting values in above equation, we get:

Hence, the concentration of solute is 0.503 mol/L