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MissTica
3 years ago
13

An ideal gas contained in a piston-cylinder assembly is compressed isothermally in an internally reversible process.

Chemistry
1 answer:
Tju [1.3M]3 years ago
7 0

Answer:

a) \Delta S

b) entropy of the sistem equal to a), entropy of the universe grater than a).

Explanation:

a) The change of entropy for a reversible process:

\delta S=\frac{\delta Q}{T}

\Delta S=\frac{Q}{T}

The energy balance:

\delta U=[tex]\delta Q- \delta W

If the process is isothermical the U doesn't change:

0=[tex]\delta Q- \delta W

\delta Q= \delta W

Q= W

The work:

W=\int_{V1}^{V2}P*dV

If it is an ideal gas:

P=\frac{n*R*T}{V}

W=\int_{V1}^{V2}\frac{n*R*T}{V}*dV

Solving:

W=n*R*T*ln(V2/V1)

Replacing:

\Delta S=\frac{n*R*T*ln(V2/V1)}{T}

\Delta S=n*R*ln(V2/V1)}

Given that it's a compression: V2<V1 and ln(V2/V1)<0. So:

\Delta S

b) The entropy change of the sistem will be equal to the calculated in a), but the change of entropy of the universe will be 0 in a) (reversible process) and in b) has to be positive given that it is an irreversible process.

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What mass of ammonia can be produced if 13.4 grams of nitrogen gas reacted ?
aivan3 [116]

Answer:

If 13.4 grams of nitrogen gas reacts we'll produce 16.3 grams of ammonia

Explanation:

Step 1: Data given

Mass of nitrogen gas (N2) = 13.4 grams

Molar mass of N2 = 28 g/mol

Molar mass of NH3 = 17.03 g/mol

Step 2: The balanced equation

N2 + 3H2 → 2NH3

Step 3: Calculate moles of N2

Moles N2 = Mass N2 / molar mass N2

Moles N2 = 13.4 grams / 28.00 g/mol

Moles N2 = 0.479 moles

Step 4: Calculate moles of NH3

For 1 mol N2 we need 3 moles H2 to produce 2 moles NH3

For 0.479 moles N2 we'll produce 2*0.479 = 0.958 moles

Step 5: Calculate mass of NH3

Mass of NH3 = moles NH3 * molar mass NH3

Mass NH3 = 0.958 moles * 17.03 g/mol

Mass NH3 = 16.3 grams

If 13.4 grams of nitrogen gas reacts we'll produce 16.3 grams of ammonia

3 0
3 years ago
What volume of 12M HCI is needed to prepare 250<br> of 0.20M HCI?
Alchen [17]

Answer: 4.2

Explanation:

M_{A}V_{A}=M_{B}V_{B}\\(12)V_{A}=(250)(0.20)\\V_{A}=\frac{(250)(0.20)}{12}=\boxed{4.2}

6 0
2 years ago
Be sure to answer all parts. For each of the following pairs of elements, state whether the binary compound they form is likely
andrew-mc [135]

Answer:

(a) Covalent bond. NF₃ (nitrogen trifluoride)

(b) Ionic bond. LiCl (lithium chloride)

Explanation:

<em>(a) N and F</em>

Nitrogen and fluorine are nonmetals, with high and similar electronegativities, so they form covalent bonds, in which they share pairs of electrons to complete the octet in their valence shell. N has 5 valence electrons so it will form 3 covalent bonds while each Cl has 7 valence electrons so it will form 1 covalent bond. As a result, the empirical formula is NF₃ (nitrogen trifluoride).

<em>(b) Li and Cl</em>

Lithium is a metal and Chlorine is a nonmetal. They have different electronegativities so they form an ionic bond, in which Cl gains 1 electron (7 valence e⁻) and Li loses 1 electron (1 valence e⁻). The empirical formula is LiCl (lithium chloride).

5 0
3 years ago
An unknown gas Q requires 2.67 times as long to effuse under the same conditions as the same amount of nitrogen gas. What is the
Misha Larkins [42]

Answer:

The correct answer is 199.66 grams per mole.

Explanation:

Based on law of effusion given by Graham, a gas rate of effusion is contrariwise proportionate to the square root of molecular mass, that is, rate of effusion of gas is inversely proportional to the square root of mass. Therefore,  

R1/R2 = √ M2/√ M1

Here rate is the rate of effusion of the gas expressed in terms of number of mole per uni time or volume, and M is the molecular mass of the gas.  

Rate Q/Rate N2 = √M of N2/ √M of Q

The molecular mass of N2 or nitrogen gas is 28 grams per mole and M of Q is molecular mass of Q and based on the question Q needs 2.67 times more to effuse in comparison to nitrogen gas, therefore, rate of Q = rate of N2/2.67

Now putting the values we get,  

rate of N2/2.67/rate of N2 = √28/ √M of Q

√M of Q = √ 28 × 2.67

M of Q = (√ 28 × 2.67)²

M of Q = 199.66 grams per mole

3 0
3 years ago
How would I fill out this chart?
Sloan [31]

Answer:

[Top row] - Chemical bonds

[2nd Row L-R] - Force, Ionic, Covalent

[3rd Row L-R] - Atoms, Lost or Gained, Shared

[4th Row L-R] - More stable, Metal and Nonmetal, Nonmetal and Nonmetal

Explanation:

<u>Chemical bonds</u> are a<u> </u><u>force</u> that hold together <u>atoms</u> in a substance to make compounds <u>more stable.</u>

<u>Chemical bonds</u> include two kinds: <u>Ionic</u> and <u>Covalent.</u>

<u>Ionic</u> in which electrons are <u>lost or gained</u> where attraction is between a <u>Metal and Nonmetal.</u>

<u>Covalent</u> in which electrons are shared where attraction is between a <u>nonmetal and nonmetal</u>.

I have been able to fill the concept map using the correct terms or phrases. The concept map talks about chemical bonds. There are two types of chemical bonds; which ionic bond and covalent bond.  

3 0
3 years ago
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