Answer:
The spring is compressed by 0.275 meters.
Explanation:
For equilibrium of the gas and the piston the pressure exerted by the gas on the piston should be equal to the sum of weight of the piston and the force the spring exerts on the piston
Mathematically we can write
we know that
Now the force exerted by an spring compressed by a distance 'x' is given by
Using the above quatities in the above relation we get
Answer: the theoretical density is 4.1109 g/cm³
Explanation:
first the image of one set of ZnS bonding in the crystal structure, we calculate the value of angle θ
θ + ∅ + 90° = 180°
θ = 90° - ∅
θ = 90° - ( 109.5° / 2 )
θ = 35.25°
next we calculate the value of x from the geometry
given that; distance angle d = 0.234
x = dsinθ
= 0.234 × sin35.25°)
= 0.135 nm = 0.135 × 10⁻⁷ cm
next we calculate the length of the unit cell
a = 4x
a = 4(0.135)
a = 0.54 nm = 0.54 × 10⁻⁷ cm
next we calculate number of formula units
n' = (no of corner atoms in unit ell × contribution of each corner atom in unit cell) + ( no of face center atom in a unit cell × contribution of each face center atom in a unit cell)
n' = 8 × 1/8) + ( 6 × 1/2)
= 1 + 3
= 4
next we calculate the theoretical density using this equation
P = [n'∑(Ac + AA)] / [Vc.NA]
= [n'∑(Ac + AA)] / [(a)³NA]
where the ∑Ac is sum of atomic weights of all cations in the formula unit( 65.41 g/mol)
∑AA is the sum of weights of all anions in the formula unit( 32.06 g/mol)
Na is the Avogadro’s number( 6.023 × 10²³ units/mole)
so we substitute
P = [4( 65.41 + 32.06)] / [ ( 0.54 × 10⁻⁷ )³ × (6.023 × 10²³)]
= 389.88 / 94.84
= 4.1109 g/cm³
therefore the theoretical density is 4.1109 g/cm³
