Answer : The time passed in years is 
Explanation :
Half-life of carbon-14 = 5730 years
First we have to calculate the rate constant, we use the formula :



Now we have to calculate the time passed.
Expression for rate law for first order kinetics is given by:

where,
k = rate constant = 
t = time passed by the sample = ?
a = initial amount of the reactant disintegrate = 15.3
a - x = amount left after decay process = 14.8
Now put all the given values in above equation, we get


Therefore, the time passed in years is 
Answer : The volume of stock solution needed are, 12.5 mL
Explanation :
Formula used :

where,
are the initial molarity and volume of copper (II) chloride.
are the final molarity and volume of stock solution of copper (II) chloride.
We are given:

Putting values in above equation, we get:

Hence, the volume of stock solution needed are, 12.5 mL
Answer:
2341, last option is the correct choice.
Explanation:
Boiling points of the given compounds are given as:

Best Regards!
Answer : The equilibrium concentration of
at
is,
.
Solution : Given,
Equilibrium constant, 
Initial concentration of
= 0.260 m
Let, the 'x' mol/L of
are formed and at same time 'x' mol/L of
are also formed.
The equilibrium reaction is,

Initially 0.260 m 0 0
At equilibrium (0.260 - x) x x
The expression for equilibrium constant for a given reaction is,
![K_c=\frac{[H_3O^+][C_2H_3O_2^-]}{[HC_2H_3O_2]}](https://tex.z-dn.net/?f=K_c%3D%5Cfrac%7B%5BH_3O%5E%2B%5D%5BC_2H_3O_2%5E-%5D%7D%7B%5BHC_2H_3O_2%5D%7D)
Now put all the given values in this expression, we get

By rearranging the terms, we get the value of 'x'.

Therefore, the equilibrium concentration of
at
is,
.