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RUDIKE [14]
2 years ago
6

1.

Chemistry
1 answer:
kenny6666 [7]2 years ago
5 0

<u>Answer:</u> The value of K_p is 324

<u>Explanation:</u>

We are given:

Initial pressure of S_8(g) = 1.00 atm

The chemical equation for the conversion of S_8(g) to S_2(g) follows:

                  S_8(g)\rightleftharpoons 4S_2(g)

<u>Initial:</u>          1

<u>At eqllm:</u>    1-x       4x

We are given:

Equilibrium partial pressure of S_8(g)=0.25atm

Evaluating the value of 'x', we get:

\Rightarrow (1-x)=0.25\\\\\Rightarrow x=1-0.25=0.75

The expression of K_p for the above reaction follows:

K_p=\frac{(p_{S_2})^4}{p_{S_8}}

p_{S_2}=4x=(4\times 0.75)=3atm

p_{S_8}=0.25atm

Putting values in above expression, we get:

K_p=\frac{3^4}{0.25}\\\\K_p=324

Hence, the value of K_p is 324

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3 years ago
Read 2 more answers
Find the pH of the equivalence point and the volume (mL) of 0.0372 M NaOH needed to reach the equivalence point in the titration
elixir [45]

Answer:

8.54

Explanation:

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42.2 X 0.052 = Vol. NaOH X 0.0372

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Number of miliimoles of CH3COOH = molarity X volume in ml = 42.2 X 0.052             = 2.1944 millimoles

Number of millimoles of NaOH = 58.99 X 0.0372 = 2.1944

Now CH₃COOH and NaOH reacts to give CH₃COONa according to the reaction :

CH₃COOH + NaOH ------> CH₃COONa + H₂O

1 mole of CH₃COOH reacts with 1 mole of NaOH to give 1 mole of CH₃COONa  

So 2.1944 millimoles of CH₃COOH will react with 2.1944 millimoles of NaOH to give 2.1944 millimoles of CH₃COONa

So all the acid (CH₃COOH) and base (NaOH) has been converted into salt (CH₃COONa) so there is no acid or base left.

Now molarity of CH₃COONa = number of millimoles of CH₃COONa/total volume in ml = 2.1944/(58.99 + 42.2) = 2.1944/101.19 = 0.02169 M

So using the hydrolysis equation :  

pH = 1/2 [ pKw + pKa + log c ]  

Ka for acetic acid = 1.75 X 10⁻⁵  

so pKa = -log (1.75 X 10⁻⁵) = 4.74  

Kw = 10⁻¹⁴

so pKw = -log 10⁻¹⁴ = 14

c = 0.02169  

so log c = log 0.02169 = -1.66  

putting the values....  

pH = 1/2 [14 + 4.74 - 1.66 ]  

pH = 1/2 [ 17.08] = 8.54

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