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lawyer [7]
2 years ago
7

Determine the molality of ions in a solution formed by dissolving 0.187 moles of NaCl in 456 grams of water. The density of the

solution is 1.44 g/mL
Chemistry
1 answer:
PSYCHO15rus [73]2 years ago
8 0

Answer:

Molality Ions Na⁺ = 0.410 m

Molality Ions Cl⁻ = 0.410 m

Total ion molality = 0.820 m

Explanation:

Molality (m) is defined as moles of solute that are dissolved in 1000g (1kg) of solvent. In this case, the molality of the ions is requested, so it should be borne in mind that when the NaCl salt dissolves in the water, it dissociates forming ions as follows:

NaCl ⇒Na⁺ (aq) + Cl⁻ (aq)

Therefore, <em>for each mole of salt that dissolves, you will have 1 mole of Na⁺ and 1 mole of Cl⁻ </em>

Knowing the amount of initial solute moles and the mass of water, we proceed to perform the calculations for each ion:

<em>Ions Na⁺</em>

456 g of H₂O ____ 0.187 mol Na⁺

1000 g of H₂O ____ X = 0.410 m

Calculation: 1000 g x 0.187 mol / 456 g = 0.410 mol

<em>Ions Cl⁻</em>

456 g of H₂O ____ 0.187 mol Cl⁻

1000 g of H₂O ____ X = 0.410 m

Calculation: 1000 g x 0.187 mol / 456 g = 0.410 m

If both results are added, the total molality of the ions will be obeyed:

0.410 m + 0.410 m = 0.820 m

This means that <em>for every kilogram of water, 0.820 moles of dissociated ions from NaCl are dissolved.</em>

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If you go from the Earth to the Moon, will your MASS change?
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Answer:

No matter if you are on Earth, the moon or just chilling in space, your mass does not change. But your weight depends on the gravity force; you would weigh less on the moon than on Earth, and in space you would weigh almost nothing at all.

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4) Balance the following redox reaction in an acidic solution. What are the coefficients in front of H⁺ and Fe3+ in the balanced
Kryger [21]

Answer:

- The coefficients in front of H⁺ and Fe³⁺ are 8 and 5

- There are transferred 5 moles of e-

Explanation:

This is the reaction:

Fe²⁺(aq) + MnO₄⁻(aq) → Fe³⁺(aq) + Mn²⁺(aq)

Let's think the oxidation numbers:

Fe2+ changed to Fe3+

It has increased the oxidation number → OXIDATION

Mn in MnO₄⁻ acts with +7 and it changed to Mn²⁺

It has decreased the oxidation number → REDUCTION

Let's make the half reactions:

Fe²⁺ → Fe³⁺  +  1e⁻    (it has lost 1 mol of e⁻)

MnO₄⁻ + 5e⁻ →  Mn²⁺  (it has gained 5 mol of e⁻)

Now we have to ballance the O. In acidic medium we complete with water as many oxygens we have, in the opposite side. We have 4 O in reactant side, so we fill up with 4 H2O in products side.

MnO₄⁻ + 5e⁻ →  Mn²⁺  + 4H₂O

Now we have to ballance the H, so as we have 8 H in products side, we complete with 8H⁺ in reactants, this is the complete half reaction:

8H⁺  + MnO₄⁻ + 5e⁻ →  Mn²⁺  + 4H₂O

Notice that have 1e⁻ in oxidation and 5e⁻ in reduction. We must multiply (x5) the half reaction of oxidation, so the electrons can be cancelled.

(Fe²⁺ → Fe³⁺  +  1e⁻ ) .5

5Fe²⁺ → 5Fe³⁺  +  5e⁻  

8H⁺  + MnO₄⁻ + 5e⁻ →  Mn²⁺  + 4H₂O

We sum both half reactions:

5Fe²⁺  + 8H⁺  + MnO₄⁻ + 5e⁻ →  5Fe³⁺  +  5e⁻   + Mn²⁺  + 4H₂O

The electrons are cancelled, so the ballanced reaction is this:

5Fe²⁺  + 8H⁺  + MnO₄⁻  →  5Fe³⁺  + Mn²⁺  + 4H₂O

3 0
3 years ago
When 78.6 g of urea CH4N2O are dissolved in 700. g of a certain mystery liquid X, the freezing point of the solution is 4.9 °C
iogann1982 [59]

Answer:

The van't Hoff factor of NaCl in liquid X is 1.69

Explanation:

Step 1: Data given

Mass of urea = 78.6 grams

Molar mass of urea = 60.06 g/mol

Mass of liquid X = 700 grams = 0.700 kg

he freezing point of the solution is 4.9°C lower than the freezing point of pure X

When 78.6 g of sodium chloride are dissolved in the same mass of X, the freezing point of the solution is 8.5°C lower than the freezing point of pure X.

Molar mass of NaCl = 58.44 g/mol

Step 2: Calculate moles

Moles urea = mass / molar mass

Moles urea = 78.6 grams / 60.06 g/mol

Moles urea = 1.31 moles

Moles NaCl = 78.9 grams / 58.44 g/mol

Moles NaCl = 1.35 moles

Step 3: Calculate molality

Molality = moles / mass of liquid

Molality urea = 1.31 moles / 0.700 kg

Molality = 1.87 molal

Molality NaCl = 1.35 moles / 0.700 kg

Molality NaCl = 1.92 molal

Step 4: Calculate the freezing point depression constant of X

ΔT = i*Kf*m

⇒with ΔT = the freezing point depression = 4.9 °C

⇒with i = the van't hoff factor of urea = 1

⇒with Kf =the freezing point depression consant of X = TO BE DETERMINED

⇒with m = the molality of urea solution = 1.87 molal

4.9 °C = 1 * Kf * 1.87 molal

Kf == 4.9 / 1.87

Kf = 2.62 °C/m

Step 5: Calculate the van't Hoff facotr of NaCl in X

ΔT = i*Kf*m

⇒with ΔT = the freezing point depression = 8.5 °C

⇒with i = the van't hoff factor of urea = TO BE DETERMINED

⇒with Kf =the freezing point depression consant of X = 2.62 °C/m

⇒with m = the molality of urea solution = 1.92 molal

8.5 °C = i * 2.62 °C/m * 1.92 m

i = 8.5 / (2.62 * 1.92)

i = 1.69

The van't Hoff factor of NaCl in liquid X is 1.69

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