As he began to teach inorganic chemistry, Mendeleev could not find a textbook that met his needs. Since he had already published a textbook on organic chemistry in 1861 that had been awarded the prestigious Demidov Prize, he set out to write another one. The result was Osnovy khimii (1868–71; The Principles of Chemistry), which became a classic, running through many editions and many translations. When Mendeleev began to compose the chapter on the halogen elements (chlorine and its analogs) at the end of the first volume, he compared the properties of this group of elements to those of the group of alkali metals such as sodium. Within these two groups of dissimilar elements, he discovered similarities in the progression of atomic weights, and he wondered if other groups of elements exhibited similar properties. After studying the alkaline earths, Mendeleev established that the order of atomic weights could be used not only to arrange the elements within each group but also to arrange the groups themselves. Thus, in his effort to make sense of the extensive knowledge that already existed of the chemical and physical properties of the chemical elements and their compounds, Mendeleev discovered the periodic law.
If the change in entropy of the surroundings for a process at 451 k and constant pressure is -326 j/k, then heat flow absorbed (in kj) by the system is -147.026kJ.
<h3>What is entropy? </h3>
The entropy of particle is defined as how random it move. It shows the randomness of the system or may be disorders of the system. It is used to measure the unavailable energy for performing useful work.
Unit of entropy = J/K
<h3>Formula:</h3>
∆s = ∆Q/T
where,
∆s = change in entropy of the surrounding = -326J/K
∆Q = heat absorbed from surrounding
T = Temperature = 451K
∆Q = ∆s × T
∆Q = -326 × 451
∆Q = 147,026 J
∆Q = 147.026 kJ
Thus we find that the heat absorbed by the system is 147.026 kJ.
learn more about entropy:
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Answer:
3–ethyl–4–methylhexane.
Explanation:
To name the above compound, do the following:
1. Determine the functional group of the compound.
2. Locate the longest continuous carbon chain. This gives the parent name of the compound.
3. Identify the substituent group attached to the compound.
4. Give the substituent the lowest possible count.
5. Combine the above to name the compound.
Now, we shall name the compound given in the question above as follow:
1. The compound contains only single bond. Therefore, the compound belong to the alkane family.
2. The longest continuous carbon chain is 6 i.e hexane.
3. The substituent group attached are:
i. Methyl, CH3.
ii. Ethyl, CH2CH3.
4. we shall name the substituents alphabetically i.e ethly will come before methyl. Therefore,
Ethyl is located at carbon 3.
Methy is located at carbon 4.
5. Therefore, the name of the compound is:
3–ethyl–4–methylhexane.
