Equilibrium expression is ![Keq = \frac{[H3O+][HCO3^-]}{[H2CO3]}\\](https://tex.z-dn.net/?f=Keq%20%3D%20%5Cfrac%7B%5BH3O%2B%5D%5BHCO3%5E-%5D%7D%7B%5BH2CO3%5D%7D%5C%5C)
<u>Explanation:</u>
Equilibrium expression is denoted by Keq.
Keq is the equilibrium constant that is defined as the ratio of concentration of products to the concentration of reactants each raised to the power its stoichiometric coefficients.
Example -
aA + bB = cC + dD
So, Keq = conc of product/ conc of reactant
![Keq = \frac{[C]^c [D]^d}{[A]^a [B]^b}](https://tex.z-dn.net/?f=Keq%20%3D%20%5Cfrac%7B%5BC%5D%5Ec%20%5BD%5D%5Ed%7D%7B%5BA%5D%5Ea%20%5BB%5D%5Eb%7D)
So from the equation, H₂CO₃+H₂O = H₃O+HCO₃⁻¹
![Keq = \frac{[H3O^+]^1 [HCO3^-]^1}{[H2CO3]^1 [H2O]^1}](https://tex.z-dn.net/?f=Keq%20%3D%20%5Cfrac%7B%5BH3O%5E%2B%5D%5E1%20%5BHCO3%5E-%5D%5E1%7D%7B%5BH2CO3%5D%5E1%20%5BH2O%5D%5E1%7D)
The concentration of pure solid and liquid is considered as 1. Therefore, concentration of H2O is 1.
Thus,
Therefore, Equilibrium expression is
Answer:
- <u>Cadmium has larger atomic radius than sulfur.</u>
Explanation:
Down a period, atomic radii decrease from left to right due to the increase in the number of protons and electrons across a period: when a proton is added the pull of the electrons towards the nucleus is larger, so the size of the atom decreases.
Hence, you can compare the elements that belong to a same period and predict that the atom with lower atomic number (number of protons) will haver larger atomic radius. With that:
- Oxygen and fluorine are in the period 3, being oxygen to the left of fluorine, so oxygen is larger than fluorine.
- Sulfur and chlorine are in the period 4, being sulfur to the left of chlorine, so sulfur is larger than chlorine.
Now see whan happens down a group. Atomic radius increases from top to bottom within a group due to electron shielding. That permits you to compare the size of the elements in a group:
- Fluorine and chlorine are in the same group (17), with chlorine directly below fluorine, so the atomic radius of chlorine is larger than the atomic radius of fluorine.
- Sulfur and oxygen are in the same group (16), with sulfur directlly below oxygen, so sulfur the atomic radius of sulfur is larger than the atocmi radius of oxygen.
So far, you can rank the atomic radius of sulfur, chlorine, fluorine, and oxygen, in increasing order as:
- O < F < Cl < S, concluding that O, F, and Cl have smaller atomic radius than S.
Cadmiun, Cd, is to the left and below sulfur, so both electron shielding (down a group) and increase of the number of protons (down a period) lead to predict the cadmium has a larger atomic radius than sulfur.
When heavy exercise results in too much acid in the human body, then "Lactic acid fermentation" occurs in our body. It is a metabolic process by which glucose and other six-carbon sugars <span>are converted into cellular energy and the metabolite </span>lactate, and we feel a lot of pain like burning muscles
Hope this helps!
To make sure no cracks are in the crucible and also to remove any moisture present in the crucible by the process of heating.
