The correct option is B.
Mendeleev was the one who originated the idea of arranging elements in the periodic table according to their chemical and physical properties. He left spaces in the periodic table and predicted the discovery of those elements that had not been discovered then. One of these elements is Gallium. He predicted that gallium is going to be a metal and he gave the properties that the element will possess. He also predicted that the element gallium will be placed under aluminium in the periodic table.
The freezing point of a 1.324 m solution, prepared by dissolving biphenyl into naphthalene, is 71.12 ° C.
A solution is prepared by dissolving biphenyl into naphthalene. We can calculate the freezing point depression (ΔT) for naphthalene using the following expression.
where,
- i: van 't Hoff factor (1 for non-electrolytes)
- Kf: cryoscopic constant
- m: molality
The normal freezing point of naphthalene is 80.26 °C. The freezing point of the solution is:
The freezing point of a 1.324 m solution, prepared by dissolving biphenyl into naphthalene, is 71.12 ° C.
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When we have:
Zn(OH)2 → Zn2+ 2OH- with Ksp = 3 x 10 ^-16
and:
Zn2+ + 4OH- → Zn(OH)4 2- with Kf = 2 x 10^15
by mixing those equations together:
Zn(OH)2 + 2OH- → Zn(OH)4 2- with K = Kf *Ksp = 3 x 10^-16 * 2x10^15 =0.6
by using ICE table:
Zn(OH)2 + 2OH- → Zn(OH)4 2-
initial 2m 0
change -2X +X
Equ 2-2X X
when we assume that the solubility is X
and when K = [Zn(OH)4 2-] / [OH-]^2
0.6 = X / (2-2X)^2 by solving this equation for X
∴ X = 0.53 m
∴ the solubility of Zn(OH)2 = 0.53 M
B is the answer. It is the steepest
