Answer:
a. 50ml b.10ml c. 6.097ml d. 190.1 ml
Explanation:
According to Boyle's law
Volume is inversely proportional to pressure at constant temerature
Mathematically
P1V1=P2V2
P1=Initial pressure=0.8atm
V1=Initial volume=25ml
making V2 the subject
at 0.4atm P2=0.4 atm,
V2=25×0.8/0.4
=50ml
at 2 atm V2=25×0.8/2
=10 ml
1mmHg=0.00131579
2500mmHg=3.28 atm
At 3.28 atm,V2=25×0.8/3.28
=6.097 ml
at 80.0 torr
1 torr=0.00131579
80 torr=0.1052 atm
at 0.1048 atm V2=25×0.8/0.1048
=190.1 ml
Ionic would be the answer
In general, the diffusion coefficient is inversely proportional to pressure. This is also an observed fact: gas production rates from coal seams tend to increase as the reservoir pressure goes down.
The freezing point depression is a colligative property which means that it is proportional to the number of particles dissolved.
The number of particles dissolved depends on the dissociation constant of the solutes, when theyt are ionic substances.
If you have equal concentrations of two solutions on of which is of a ionic compound and the other not, then the ionic soluton will contain more particles (ions) and so its freezing point will decrease more (will be lower at end).
In this way you can compare the freezing points of solutions of KCl, Ch3OH, Ba(OH)2, and CH3COOH, which have the same concentration.
As I explained the solution that produces more ions will exhibit the greates depression of the freezing point, leading to the lowest freezing point.
In this case, Ba(OH)2 will produce 3 iones, while KCl will produce 2, CH3OH will not dissociate into ions, and CH3COOH will have a low dissociation constant.
Answer: Then, you can predict that Ba(OH)2 solution has the lowest freezing point.
