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Charra [1.4K]
3 years ago
9

250 g H 2 SO 4 completely reacted with aluminum?

Chemistry
1 answer:
Rasek [7]3 years ago
3 0

Answer: 290 g of aluminium sulphate is produced.

Explanation:

To calculate the moles :

\text{Moles of solute}=\frac{\text{given mass}}{\text{Molar Mass}}    

\text{Moles of} H_2SO_4=\frac{250g}{98g/mol}=2.55moles

The balanced chemical reaction is:

2Al(s)+3H_2SO_4(aq)\rightarrow Al_2(SO_4)_3(aq)+3H_2(g)

According to stoichiometry :

3 moles of H_2SO_4 produce  = 1 mole of Al_2(SO_4)_3

Thus 2.55 moles of H_2SO_4 will require=\frac{1}{3}\times 2.55=0.85moles  of Al_2(SO_4)_3

Mass of Al_2(SO_4)_3=moles\times {\text {Molar mass}}=0.85moles\times 342g/mol=290g

Thus 290 g of aluminium sulphate is produced.

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Use the data given below to construct a Born-Haber cycle to determine the heat of formation of KCl. Δ H°(kJ) K(s) → K(g) 89 K(g)
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Explanation:

The net equation will be as follows.

          K(s) + Cl_{2}(g) \rightarrow KCl(s)

So, we are required to find \Delta H_{formation} for this reaction.

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Step 1:  Convert K from solid state to gaseous state

          K(s) \rightarrow K(g),    \Delta H_{1} = 89 kJ

Step 2:  Ionization of gaseous K

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            \frac{1}{2} Cl_{2}(g) \rightarrow Cl(g),   \Delta H_{3} = \frac{244}{2} = 122 KJ

Step 4: Iozination of chlorine atom.

              Cl(g) + e^{-} \rightarro Cl^{-}(g),      H_{4} = -349 KJ

Step 5:  Add K^{+} ion and Cl^{-} ion formed above to get KCl .

              K^{+}(g) + Cl^{-}(g) \rightarrow KCl(s),   H_{5} = -717 KJ

Now, using Born-Haber cycle, value of enthalpy of the formation is calculated as follows.

      \Delta H_{f} = \DeltaH_{1} + \Delta H_{2} + \Delta H_{3} + \Delta H_{4} + \Delta H_{5}

                  = 89 + 418 + 122 - 349 - 717

                  = - 437 KJ/mol

Thus, we can conclude that the heat of formation of KCl is - 437 KJ/mol.

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