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lina2011 [118]
3 years ago
6

The complete combustion of octane, C8H18, the main component of gasoline, proceeds as follows: 2C8H18 (l) 25 O2(g) --> 16 CO2

(g) 18 H2O (g)
a. How many moles of 02 are needed to burn 1.50 mol of C8H18?
b. How many grams of 02 are needed to burn 10.0 g of C8H18?
c. Octane has a density of 0.692 g/ml at 20 degrees Celsius. How many grams of 02 are required to burn 15.0 gal of C8H18 (the capacity of an average file tank)?
Chemistry
2 answers:
viva [34]3 years ago
8 0

Answer:

a. 18.75 mol of O₂

b. 35.008 g   of O₂

c. 137868 g   of O₂

Explanation:

a.

Based on the balanced equation the molar ratio of C₈H₁₈ : O₂(g) = 2:25  Therefore, 1.50 mol of C₈H₁₈ = 25/2 x 1.5 = 18.75 mol of O₂

b.

Given, mass of C₈H₁₈ = 10.0 g  

Molar mass of C₈H₁₈ = (12 x 8) + (18 x 1) = 114 g/mol

Moles of C₈H₁₈ = 10.0 g/ 114 g/mol = 0.08772

Based on the balanced equation the molar ratio of C₈H₁₈ : O₂(g) = 2:25  

Therefore, 0.08772 mol of C₈H₁₈ = 25/2 x 0.08772 = 1.0965 mol of O₂

Molar mass of O₂ = 32 g/mol

Mass of O₂ = 1.0965 mol x 32 g/mol = 35.008 g  

c.

Given, density of C₈H₁₈ = 0.692 g/ml

Volume of C₈H₁₈ = 15.0 gal

Volume of C₈H₁₈ = 15.0 gal x 3785.41 ml/ 1 gal = 56781.15 ml

Mass of C₈H₁₈ = density of C₈H₁₈ x Volume of C₈H₁₈

                         = 0.692 g/ml x 56781.15 ml = 39292.5 g  

Molar mass of C₈H₁₈ = 114 g/mol

Moles of C₈H₁₈ = 39292.5 g / 114 g/mol = 344.67 mol

Based on the balanced equation the molar ratio of C₈H₁₈ : O₂(g) = 2:25  

Therefore, 344.67 mol of C₈H₁₈ = 25/2 x 344.67 = 4308.375 mol of O₂

Molar mass of O₂ = 32 g/mol

Mass of O₂ = 4308.375 mol x 32 g/mol = 137868 g  

Svet_ta [14]3 years ago
7 0
The ratio of mole number of the reactants and products is equal to the coefficients. So the answer is a. 18.75 mol. b. 35.1 g. c. 1.38 * 10^5 g.
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<u>For a:</u> The standard Gibbs free energy of the reaction is -347.4 kJ

<u>For b:</u> The standard Gibbs free energy of the reaction is 746.91 kJ

<u>Explanation:</u>

Relationship between standard Gibbs free energy and standard electrode potential follows:

\Delta G^o=-nFE^o_{cell}           ............(1)

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The given chemical equation follows:

2Ce^{4+}(aq.)+3I^{-}(aq.)\rightarrow 2Ce^{3+}(aq.)+I_3^-(aq.)

<u>Oxidation half reaction:</u>   Ce^{4+}(aq.)\rightarrow Ce^{3+}(aq.)+e^-       ( × 2)

<u>Reduction half reaction:</u>   3I^_(aq.)+2e^-\rightarrow I_3^-(aq.)

We are given:

n=2\\E^o_{cell}=+1.08V\\F=96500

Putting values in equation 1, we get:

\Delta G^o=-2\times 96500\times (+1.80)=-347,400J=-347.4kJ

Hence, the standard Gibbs free energy of the reaction is -347.4 kJ

  • <u>For b:</u>

The given chemical equation follows:

6Fe^{3+}(aq.)+2Cr^{3+}+7H_2O(l)(aq.)\rightarrow 6Fe^{2+}(aq.)+Cr_2O_7^{2-}(aq.)+14H^+(aq.)

<u>Oxidation half reaction:</u>   Fe^{3+}(aq.)\rightarrow Fe^{2+}(aq.)+e^-       ( × 6)

<u>Reduction half reaction:</u>   2Cr^{2+}(aq.)+7H_2O(l)+6e^-\rightarrow Cr_2O_7^{2-}(aq.)+14H^+(aq.)

We are given:

n=6\\E^o_{cell}=-1.29V\\F=96500

Putting values in equation 1, we get:

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Hence, the standard Gibbs free energy of the reaction is 746.91 kJ

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