What is the freezing point of a solution made with 1.31 mol of CHCl3 in 530.0 g of CCl4 (Kf =29.8 degrees C/m, Freezing point of
1 answer:
73.606 °C is the freezing point of the solution made with with 1.31 mol of CHCl3 in 530.0 g of CCl4.
Explanation:
Data given:
number of moles of CHCl3 = 1.31 moles
mass of solvent CHCl3 = 530 grams or 0.53 kg
Kf = 29.8 degrees C/m
freezing point of pure solvent or CCl4 = -22.9 degrees
freezing point = ?
The formula used to calculate the freezing point of the mixture is
ΔT = iKf.m
m= molality
molality =
putting the value in the equation:
molality=
= 2.47 M
Putting the values in freezing point equation
ΔT = 1.31 x 29.8 x 2.47
ΔT = 73.606 degrees
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Answer:
- Mass of monobasic sodium phosphate = 1.857 g
- Mass of dibasic sodium phosphate = 1.352 g
Explanation:
<u>The equilibrium that takes place is:</u>
H₂PO₄⁻ ↔ HPO₄⁻² + H⁺ pka= 7.21 (we know this from literature)
To solve this problem we use the Henderson–Hasselbalch (<em>H-H</em>) equation:
pH = pka +
In this case [A⁻] is [HPO₄⁻²], [HA] is [H₂PO₄⁻], pH=7.0, and pka = 7.21
If we use put data in the <em>H-H </em>equation, and solve for [HPO₄⁻²], we're left with:
From the problem, we know that [HPO₄⁻²] + [H₂PO₄⁻] = 0.1 M
We replace the value of [HPO₄⁻²] in this equation:
0.616 * [H₂PO₄⁻] + [H₂PO₄⁻] = 0.1 M
1.616 * [H₂PO₄⁻] = 0.1 M
[H₂PO₄⁻] = 0.0619 M
With the value of [H₂PO₄⁻] we can calculate [HPO₄⁻²]:
[HPO₄⁻²] + 0.0619 M = 0.1 M
[HPO₄⁻²] = 0.0381 M
With the concentrations, the volume and the molecular weights, we can calculate the masses:
- Molecular weight of monobasic sodium phosphate (NaH₂PO₄)= 120 g/mol.
- Molecular weight of dibasic sodium phosphate (Na₂HPO₄)= 142 g/mol.
- mass of NaH₂PO₄ = 0.0619 M * 0.250 L * 120 g/mol = 1.857 g
- mass of Na₂HPO₄ = 0.0381 M * 0.250 L * 142 g/mol = 1.352 g