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lara [203]
3 years ago
13

What is the free energy change in kJ/mol for the process below at 43.9 °C when the concentration of A =0.88 M, B = 0.49 M and C

= 0.69 M? g
Chemistry
1 answer:
nata0808 [166]3 years ago
8 0

Answer:

-15.5 kJ/mol

Explanation:

2A ⇄ 2B + C

$ K = \frac{[C][B]^2}{[A]^2} $

   = $ \frac{(0.69)(0.49)^2}{0.88^2} $

  = 0.21

T = $ 43.9^{\circ} $C

   = (273 + 43.9) K  =  316.9 K

$ \Delta G^{\circ} = -19.4 $ kJ/mol

R = 8.314 J/k-mol  =  0.008314 kJ/k-mol

$ \Delta G = \Delta G^{\circ} - RT \ln K $

     $ =-19.4 - 0.008314 \times 316.9 \ln (0.21) $

     = -15.5 kJ/ mol

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14.16 μM is the molarity of the red dye solution at the optimal wavelength 519nm and absorbance value 0.945.

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1 L of solution contains 1.4163\times 10^{-5} moles of red dye.

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c) In order to dilute red dye solution by 5 times, we will need to add 1 L of water to solution of given concentration.

Concentration of red dye solution = c=1.4163\times 10^{-5} M

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c'=2.83\times 10^{-6} M

The final concentration of the diluted solution is 2.83\times 10^{-6} M

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