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V125BC [204]
3 years ago
7

Ethylenediamine (en) forms an octahedral complex with Ni2+(aq) with the formula [Ni(en)3]2+. Ni2+(aq) + 3 en ⇌ [Ni(en)3]2+(aq) K

f = 4.0 x 1018 If there are 0.16 mol [Ni(en)3]2+ and 0.80 mol ethylenediamine at equilibrium in a 2-L solution, what is the concentration of Ni2+(aq) in the solution?
Chemistry
1 answer:
yawa3891 [41]3 years ago
6 0

Answer:

3.125\times 10^{-19} mol/L is the concentration of Ni^{2+}(aq) in the solution.

Explanation:

Ni^{2+}(aq) + 3 en\rightleftharpoons [Ni(en)_3]^{2+}(aq)

Concentration of nickel ion = [Ni^{2+}]=x

Concentration of nickel complex= [[Ni(en)_3]^{2+}]=\frac{0.16 mol}{2 L}=0.08 mol/L

Concentration of ethylenediamine = [en]=\frac{0.80 mol}{2 L}=0.40 mol/L

The formation constant of the complex = K_f=4.0\times 10^{18}

The expression of formation constant is given as:

K_f=\frac{[[Ni(en)_3]^{2+}]}{[Ni^{2+}][en]^3}

4.0\times 10^{18}=\frac{0.08 mol/L}{x\times (0.40 mol/L)^3}

x=\frac{0.08 mol/L}{4.0\times 10^{18}\times (0.40 mol/L)^3}

x=3.125\times 10^{-19} mol/L

3.125\times 10^{-19} mol/L is the concentration of Ni^{2+}(aq) in the solution.

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Limiting Reactant Worksheet
faltersainse [42]

Answer:

a) 1.61 mol

b) Al is limiting reactant

c) HBr is in excess

Explanation:

Given data:

Moles of Al = 3.22 mol

Moles of HBr = 4.96 mol

Moles of H₂ formed = ?

What is limiting reactant =

What is excess reactant = ?

Solution:

Chemical equation:

2Al  + 2HBr  → 2AlBr + H₂

Now we will compare the moles:

                Al              :               H₂

                  2              :               1

                 3.22         :            1/2×3.22 = 1.61 mol

                HBr            :              H₂

                 2                :               1

                4.96            :          1/2×4.96 = 2.48 mol      

The number of moles of H₂ produced by Al are less it will be limiting reactant while HBr is present in excess.

Moles of H₂ :

Number of moles of H₂ = 1.61 mol

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Wha do u do when u get in a fight wit yo best friend?
antiseptic1488 [7]
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Brilliant_brown [7]

Answer:

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Explanation:

Hello there!

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