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3 years ago

14

What os the term for the smallest bit into which chemical substance can be divided and still have the properties of that substan

ce
A :eletron B:molecule c:atom D:ion

1 answer:

Ostrovityanka [42]3 years ago

3 0

That's a molecule of the substance. You can break the molecule down further, into the atoms that make it up, but those don't have the properties of the original 'compound'.

Here's an example:

-- Sodium is a soft, slippery metal, that explodes when water touches it.

-- Chlorine is a poisonous green gas.

When an atom of Sodium and an atom of Chlorine combine, they make one molecule of a substance called "Sodium Chloride". That's SALT ! It isn't green, it isn't a gas, it isn't poisonous, it isn't soft and slippery, and it doesn't explode when water touches it.

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<u>Answer:</u> The change in entropy of the given process is 1324.8 J/K

<u>Explanation:</u>

The processes involved in the given problem are:

$1.)H_2O(s)(-18^oC,255K)\rightarrow H_2O(s)(0^oC,273K)\\2.)H_2O(s)(0^oC,273K)\rightarrow H_2O(l)(0^oC,273K)\\3.)H_2O(l)(0^oC,273K)\rightarrow H_2O(l)(100^oC,373K)\\4.)H_2O(l)(100^oC,373K)\rightarrow H_2O(g)(100^oC,373K)\\5.)H_2O(g)(100^oC,373K)\rightarrow H_2O(g)(120^oC,393K)$

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To calculate the entropy change for same phase at different temperature, we use the equation:

$\Delta S=m\times C_{p,m}\times \ln (\frac{T_2}{T_1})$ .......(1)

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$\Delta S$ = Entropy change

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m = mass of ice = 0.15 kg = 150 g (Conversion factor: 1 kg = 1000 g)

$T_2$ = final temperature

$T_1$ = initial temperature

To calculate the entropy change for different phase at same temperature, we use the equation:

$\Delta S=m\times \frac{\Delta H_{f,v}}{T}$ .......(2)

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$\Delta S$ = Entropy change

m = mass of ice

$\Delta H_{f,v}$ = enthalpy of fusion of vaporization

T = temperature of the system

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<u>For process 1:</u>

We are given:

$m=150g\\C_{p,s}=2.06J/gK\\T_1=255K\\T_2=273K$

Putting values in equation 1, we get:

$\Delta S_1=150g\times 2.06J/g.K\times \ln(\frac{273K}{255K})\\\\\Delta S_1=21.1J/K$

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We are given:

$m=150g\\\Delta H_{fusion}=334.16J/g\\T=273K$

Putting values in equation 2, we get:

$\Delta S_2=\frac{150g\times 334.16J/g}{273K}\\\\\Delta S_2=183.6J/K$

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We are given:

$m=150g\\C_{p,l}=4.184J/gK\\T_1=273K\\T_2=373K$

Putting values in equation 1, we get:

$\Delta S_3=150g\times 4.184J/g.K\times \ln(\frac{373K}{273K})\\\\\Delta S_3=195.9J/K$

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We are given:

$m=150g\\\Delta H_{vaporization}=2259J/g\\T=373K$

Putting values in equation 2, we get:

$\Delta S_2=\frac{150g\times 2259J/g}{373K}\\\\\Delta S_2=908.4J/K$

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We are given:

$m=150g\\C_{p,g}=2.02J/gK\\T_1=373K\\T_2=393K$

Putting values in equation 1, we get:

$\Delta S_5=150g\times 2.02J/g.K\times \ln(\frac{393K}{373K})\\\\\Delta S_5=15.8J/K$

Total entropy change for the process = $\Delta S_1+\Delta S_2+\Delta S_3+\Delta S_4+\Delta S_5$

Total entropy change for the process = $[21.1+183.6+195.9+908.4+15.8]J/K=1324.8J/K$

Hence, the change in entropy of the given process is 1324.8 J/K

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