If Ka for HBrO is 2. 8×10^−9 at 25°C, then the value of Kb for BrO− at 25°C is 3.5× 10^(-6).
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What is base dissociation constant?
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The base dissociation constant (Kb) is defined as the measurement of the ions which base can dissociate or dissolve in the aqueous solution. The greater the value of base dissociation constant greater will be its basicity an strength.
The dissociation reaction of hydrogen cyanide can be given as
HCN --- (H+) + (CN-)
Given,
The value of Ka for HCN is 2.8× 10^(-9)
The correlation between base dissociation constant and acid dissociation constant is
Kw = Ka × Kb
Kw = 10^(-14)
Substituting values of Ka and Kw,
Kb = 10^(-14) /{2.8×10^(-9) }
= 3.5× 10^(-6)
Thus, we find that if Ka for HBrO is 2. 8×10^−9 at 25°C, then the value of Kb for BrO− at 25°C is 3.5× 10^(-6).
DISCLAIMER: The above question have mistake. The correct question is given as
Question:
Given that Ka for HBrO is 2. 8×10^−9 at 25°C. What is the value of Kb for BrO− at 25°C?
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Ring opening of epoxide with acid:
In the presence of base, the nucleophile attacks the epoxide ring at more substituted site and inverse stereochemistry takes place.(check file 2 attached)
Ring opening of epoxide with base:
The backside attack of nucleophile takes place in less substituted site and then it undergoes protonation to form a product.
(check file 2 attached)
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