Answer:
25,050 calories.
Explanation:
A calorie is the amount of energy needed to raise the temperature of one gram of water 1 degree centigrade. If we are raising 835 grams of water 30 degrees then we multiply 835*30 to get 25,050 calories.
<u>Answer:</u> The standard free energy change of formation of
is 92.094 kJ/mol
<u>Explanation:</u>
We are given:

Relation between standard Gibbs free energy and equilibrium constant follows:

where,
= standard Gibbs free energy = ?
R = Gas constant = 
T = temperature = ![25^oC=[273+25]K=298K](https://tex.z-dn.net/?f=25%5EoC%3D%5B273%2B25%5DK%3D298K)
K = equilibrium constant or solubility product = 
Putting values in above equation, we get:

For the given chemical equation:

The equation used to calculate Gibbs free change is of a reaction is:
![\Delta G^o_{rxn}=\sum [n\times \Delta G^o_f_{(product)}]-\sum [n\times \Delta G^o_f_{(reactant)}]](https://tex.z-dn.net/?f=%5CDelta%20G%5Eo_%7Brxn%7D%3D%5Csum%20%5Bn%5Ctimes%20%5CDelta%20G%5Eo_f_%7B%28product%29%7D%5D-%5Csum%20%5Bn%5Ctimes%20%5CDelta%20G%5Eo_f_%7B%28reactant%29%7D%5D)
The equation for the Gibbs free energy change of the above reaction is:
![\Delta G^o_{rxn}=[(2\times \Delta G^o_f_{(Ag^+(aq.))})+(1\times \Delta G^o_f_{(S^{2-}(aq.))})]-[(1\times \Delta G^o_f_{(Ag_2S(s))})]](https://tex.z-dn.net/?f=%5CDelta%20G%5Eo_%7Brxn%7D%3D%5B%282%5Ctimes%20%5CDelta%20G%5Eo_f_%7B%28Ag%5E%2B%28aq.%29%29%7D%29%2B%281%5Ctimes%20%5CDelta%20G%5Eo_f_%7B%28S%5E%7B2-%7D%28aq.%29%29%7D%29%5D-%5B%281%5Ctimes%20%5CDelta%20G%5Eo_f_%7B%28Ag_2S%28s%29%29%7D%29%5D)
We are given:

Putting values in above equation, we get:
![285.794=[(2\times 77.1)+(1\times \Delta G^o_f_{(S^{2-}(aq.))})]-[(1\times (-39.5))]\\\\\Delta G^o_f_{(S^{2-}(aq.))=92.094J/mol](https://tex.z-dn.net/?f=285.794%3D%5B%282%5Ctimes%2077.1%29%2B%281%5Ctimes%20%5CDelta%20G%5Eo_f_%7B%28S%5E%7B2-%7D%28aq.%29%29%7D%29%5D-%5B%281%5Ctimes%20%28-39.5%29%29%5D%5C%5C%5C%5C%5CDelta%20G%5Eo_f_%7B%28S%5E%7B2-%7D%28aq.%29%29%3D92.094J%2Fmol)
Hence, the standard free energy change of formation of
is 92.094 kJ/mol
1) Find the molar mass of sucrose: 12*12 + 22*1 + 11*16 = 342 g/mol
2) Multiply the molar mass by the number of mols: 0.185 mol * 342 g/mol = 63.27 g
Answer:
1. Core electrons = 1s²; Valence electrons = 2s² and 2p³
2. Core electrons = 1s², 2s²,m2p⁶; Valence electrons = 3s² and 3p⁵
Explanation:
The electrons in an atom of an element are generally divided into two groups: the core electrons and the Valence electrons
Valence electrons are those electrons which are located of or found in the outermost shell or highest energy level of an atom. These valence electrons are the one that determine the chemical reactivity of an atom as they can participate in bond formation between atoms of the same element or with atoms of other elements. The valence electrons also, generally determine the group to which an element will belong to.
Core electrons on the other hand, are those electrons which are found within the innermost shell or lowest energy levels of the atom. They are strongly attracted to the nucleus of atom and do not take part in chemical bonding. However, they play the important role of shieldingnthe valence electrons from the positive charge of the nucleus thereby assisting the valence electrons in bond formation.
For a general reaction,

General expression for rate law will be:
![r=k[A]^{a}[B]^{b}](https://tex.z-dn.net/?f=r%3Dk%5BA%5D%5E%7Ba%7D%5BB%5D%5E%7Bb%7D)
Here, r is rate of the reaction, k is rate constant, a is order with respect to reactant A and b is order with respect to reactant B.
The reaction is first order with respect to
, second order with respect to
and zero order with respect to
.
According to above information, expression for rate law will be:
![r=k[BrO_{3}^{-}]^{1}[Br^{-}]^{2}[H^{+}]^{0}](https://tex.z-dn.net/?f=r%3Dk%5BBrO_%7B3%7D%5E%7B-%7D%5D%5E%7B1%7D%5BBr%5E%7B-%7D%5D%5E%7B2%7D%5BH%5E%7B%2B%7D%5D%5E%7B0%7D)
Or,
...... (1)
- When concentration of
get doubled, rate of the reaction becomes,
...... (2)
Dividing (2) by (1)
![\frac{r^{'}}{r}=\frac{2k[BrO_{3}^{-}][Br^{-}]^{2}}{k[BrO_{3}^{-}][Br^{-}]^{2}}=2](https://tex.z-dn.net/?f=%5Cfrac%7Br%5E%7B%27%7D%7D%7Br%7D%3D%5Cfrac%7B2k%5BBrO_%7B3%7D%5E%7B-%7D%5D%5BBr%5E%7B-%7D%5D%5E%7B2%7D%7D%7Bk%5BBrO_%7B3%7D%5E%7B-%7D%5D%5BBr%5E%7B-%7D%5D%5E%7B2%7D%7D%3D2)
Or,

Thus, rate of the reaction also get doubled.
- When the concentration of
is halved, the rate of reaction becomes
Or,
...... (3)
Dividing (3) by (1)
![\frac{r^{"}}{r}=\frac{1/4k[BrO_{3}^{-}][Br^{-}]^{2}}{k[BrO_{3}^{-}][Br^{-}]^{2}}=\frac{1}{4}](https://tex.z-dn.net/?f=%5Cfrac%7Br%5E%7B%22%7D%7D%7Br%7D%3D%5Cfrac%7B1%2F4k%5BBrO_%7B3%7D%5E%7B-%7D%5D%5BBr%5E%7B-%7D%5D%5E%7B2%7D%7D%7Bk%5BBrO_%7B3%7D%5E%7B-%7D%5D%5BBr%5E%7B-%7D%5D%5E%7B2%7D%7D%3D%5Cfrac%7B1%7D%7B4%7D)
Or,

Thus, rate of reaction becomes 1/4th of the initial rate.
- When the concentration of
is tripled:
Since, the rate expression does not have concentration of
, it is independent of it. Thus, any change in the concentration will not affect the rate of reaction and rate of reaction remains the same as in equation (1).