Identify the compound with the highest percent ionic character. identify the compound with the highest percent ionic character.
1 answer:
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Answer:
p-fluoronitrobenzene and sodium phenoxide is more appropriate
Explanation:
An ipso substitution is required to form p-nitrophenyl phenyl ether.
For this ipso substitution, an alkoxide anion needs to attack as a nucleophile at the carbon atom attached to fluorine atom and thereby substitute that F atom.
p-nitrophenoxide is an weak nucleophile as compared to phenoxide due to presence of electron withdrawing resonating effect of nitro group at para position.
p-fluoronitrobenzene is a good choice for nucleophilic attack by alkoxide anion as compared to fluorobenzene due to higher positive charge density at carbon atom directly attached to F atom. Higher positive charge density arises due to presence of electron withdrawing resonating effect og nitro group at para position.
So, p-fluoronitrobenzene and sodium phenoxide is more appropriate
Answer:
The boiling point is 308.27 K (35.27°C)
Explanation:
The chemical reaction for the boiling of titanium tetrachloride is shown below:
Ti ⇒ Ti
ΔH° (Ti
) = -804.2 kJ/mol
ΔH° (Ti
) = -763.2 kJ/mol
Therefore,
ΔH° = ΔH°
(Ti
) - ΔH°
(Ti
) = -763.2 - (-804.2) = 41 kJ/mol = 41000 J/mol
Similarly,
s°(Ti) = 221.9 J/(mol*K)
s°(Ti) = 354.9 J/(mol*K)
Therefore,
s° = s° (Ti) - s°(Ti
) = 354.9 - 221.9 = 133 J/(mol*K)
Thus, T = ΔH° /s° = [41000 J/mol]/[133 J/(mol*K)] = 308. 27 K or 35.27°C
Therefore, the boiling point of titanium tetrachloride is 308.27 K or 35.27°C.