Steps 1 and 3 are correct rate
Here we apply the Clausius-Clapeyron equation:
ln(P₁/P₂) = ΔH/R x (1/T₂ - 1/T₁)
The normal vapor pressure is 4.24 kPa (P₁)
The boiling point at this pressure is 293 K (P₂)
The heat of vaporization is 39.9 kJ/mol (ΔH)
We need to find the vapor pressure (P₂) at the given temperature 355.3 K (T₂)
ln(4.24/P₂) = 39.9/0.008314 x (1/355.3 - 1/293)
P₂ = 101.2 kPa
The correct answers are
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Answer:
13.4 (w/w)% of CaCl₂ in the mixture
Explanation:
All the Cl⁻ that comes from CaCl₂ (Calcium chloride) will be precipitate in presence of AgNO₃ as AgCl.
To solve this problem we must find the moles of AgCl = Moles of Cl⁻. As 2 moles of Cl⁻ are in 1 mole of CaCl₂ we can find the moles of CaCl₂ and its mass in order to find mass percent of calcium chloride in the original mixture.
<em>Moles AgCl - Molar mass: 143.32g/mol -:</em>
0.535g * (1mol / 143.32g) = 3.733x10⁻³ moles AgCl = Moles Cl⁻
<em>Moles CaCl₂:</em>
3.733x10⁻³ moles Cl⁻ * (1mol CaCl₂ / 2mol Cl⁻) = 1.866x10⁻³ moles CaCl₂
<em>Mass CaCl₂ -Molar mass: 110.98g/mol-:</em>
1.866x10⁻³ moles CaCl₂ * (110.98g/mol) = 0.207g of CaCl₂ in the mixture
That means mass percent of CaCl₂ is:
0.207g CaCl₂ / 1.55g * 100 =
<h3>13.4 (w/w)% of CaCl₂ in the mixture</h3>
Answer:
Explanation has been given below
Explanation:
- In diaxial conformation of cis-1,3-disubstituted cyclohexane, 4 gauche-butane interactions along with syn-diaxial interaction are present. Hence it readily gets converted to diequitorial conformation where no such gauche-butane interaction is present
- In two possible conformations of trans-1,3-disubstituted cyclohexane, 2 gauche-butane interactions are present in each of them.
- Hence cis-1,3-disubstituted cyclohexane exists almost exclusively in diequitorial form. But trans-1,3-disubstituted cyclohexane has no such option.
- Trans-1,3-disubstituted cyclohexane experiences gauche butane interaction in each of the two conformations.
- Therefore cis-1,3-disubstituted cyclohexane is more stable than trans conformation